CID 11980975

Base Information

• Chemical Name: CID 11980975
• CAS No.: 36309-88-3
• Molecular Formula: C72H48 N6 Ru . 2 Cl
• Molecular Weight: 1169.19
• Hs Code.: 29339900
• European Community (EC) Number: 609-229-6
• Mol file: 36309-88-3.mol

Synonyms:36309-88-3;tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(ii) dichloride;4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);dichloride;tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(ii)dichloride;CID 11980975;AT26877;A900992;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride

Chemical Property of CID 11980975

Chemical Property:

• Vapor Pressure: 2.63E-11mmHg at 25°C
• Melting Point: 275-279°C (dec.)
• Boiling Point: 543.1°Cat760mmHg
• Flash Point: 242.1°C
• PSA: 77.34000
• Density: g/cm³
• LogP: 19.73000
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: DMF: soluble
• Water Solubility.: Soluble in alcohol and dimethylformamide. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 6
• Exact Mass: 1168.236091
• Heavy Atom Count: 81
• Complexity: 409

Purity/Quality:

99% ^*data from raw suppliers

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II)dichloridecomplex ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.[Cl-].[Cl-].[Ru+2]
• Uses: Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex is a luminescent oxygen probe.
• Description: Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium II dichloride complex is a luminescent probe (absorption λmax: 455 nm, luminescence λmax: 613 nm) widely used for detection and quantitation of oxygen. The dye is strongly reduced by molecular oxygen as a result of dynamic quenching; thus oxygen detection can be based on either measurement of intensity or decay time. This oxygen probe has been used to optimize optical oxygen sensors, to measure oxygen flux through tissues and in skin tumors, and for oxygen imaging.

Technology Process of CID 11980975

There total 4 articles about CID 11980975 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) hexafluorophosphate + tetrabutyl-ammonium chloride (1112-67-0) → ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride (36309-88-3)

Guidance literature:

In acetone;

DOI:10.1039/c9sc05671h

Reference yield: 89.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + bathophenanthroline (1662-01-7) → ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride (36309-88-3)

Guidance literature:

In N,N-dimethyl-formamide; other Radiation; subjected to 300-W microwave irradn. at 250°C for 5 min; cooled, pptd. (CH2Cl2/Et2O), recrystd.;

DOI:10.1021/ja0565065

Reference yield: 85.0%

ruthenium(III) chloride trihydrate + bathophenanthroline (1662-01-7) → ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride (36309-88-3)

Guidance literature:

In 1,2-dimethoxyethane; for 72h; Inert atmosphere; Reflux;

DOI:10.1016/j.saa.2014.04.060

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

bathophenanthroline

tetrabutyl-ammonium chloride

Refernces

• 1、 Babu, Eththilu,Muthu Mareeswaran, Paulpandian,Singaravadivel, Subramanian,Bhuvaneswari, Jayaraman,Rajagopal, Seenivasan. "A selective, long-lived deep-red emissive ruthenium(II) polypyridine complexes for the detection of BSA". . p. 553 - 560. Retrieved 2014.
• 2、 Hu, Liangyu,Li, Kun,Liu, Minghua,Shang, Weili,Zhu, Xuefeng. "Emerging Cubic Chirality in γCD-MOF for Fabricating Circularly Polarized Luminescent Crystalline Materials and the Size Effect". . p. 4953 - 4958. Retrieved 2020.