K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)]

Base Information

• Chemical Name: K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)]
• CAS No.: 178691-66-2
• Molecular Formula: C₁₂H₂₄KO₆*C₁₇H₁₀FeO₅P
• Molecular Weight: 684.501
• Mol file: 178691-66-2.mol

Synonyms:K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)]

Chemical Property of K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)]

There total 1 articles about K(C₁₂H₂₄O₆)⁽¹⁺⁾*Fe(CO)4(COP(C₆H₅)2)^(1-) = [K(C₁₂H₂₄O₆)][Fe(CO)4(COP(C₆H₅)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + 18-crown-6 ether (17455-13-9) + potassium diphenylphosphine (15475-27-1,4346-39-8) → K(C12H24O6)(1+)*Fe(CO)4(COP(C6H5)2)(1-) = [K(C12H24O6)][Fe(CO)4(COP(C6H5)2)] (178691-66-2)

Guidance literature:

In tetrahydrofuran; (argon); addn. of KPPh2 in THF at -78°C to Fe(CO)5 and 18-crown-6within 20 min with stirring; prepd. as soln.;

Reference yield:

K(C12H24O6)(1+)*Fe(CO)4(COP(C6H5)2)(1-) = [K(C12H24O6)][Fe(CO)4(COP(C6H5)2)] (178691-66-2) + trimethyltin(IV)chloride (1066-45-1) → iron pentacarbonyl (13463-40-6,37220-42-1) + (trimethylstannyl)diphenylphosphine (1213-51-0)

Guidance literature:

In tetrahydrofuran; byproducts: (Ph2P)2; (argon); -78°C; removal of volatiles (high vac.), extn. (toluene);

Reference yield:

K(C12H24O6)(1+)*Fe(CO)4(COP(C6H5)2)(1-) = [K(C12H24O6)][Fe(CO)4(COP(C6H5)2)] (178691-66-2) → K(C12H24O6)(1+)*Fe(CO)4(P(C6H5)2)(1-)*C4H8O = [K(C12H24O6)][Fe(CO)4(P(C6H5)2)]*C4H8O

Guidance literature:

In tetrahydrofuran; byproducts: (Ph2P)2; (argon); slow warming from -78°C to room temp., filtration, concn. in high vac., layering with pentane (some d); recrystn. (THF/pentane); elem. anal.;

upstream raw materials:

iron pentacarbonyl

18-crown-6 ether

potassium diphenylphosphine

Downstream raw materials:

iron pentacarbonyl

(trimethylstannyl)diphenylphosphine