(E)-undec-1-en-1-ylbenzenecolorless

Base Information

• Chemical Name: (E)-undec-1-en-1-ylbenzenecolorless
• CAS No.: 107224-27-1
• Molecular Formula: C₁₇H₂₆
• Molecular Weight: 230.393
• Mol file: 107224-27-1.mol

Synonyms:(E)-undec-1-en-1-ylbenzenecolorless

Chemical Property of (E)-undec-1-en-1-ylbenzenecolorless

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-undec-1-en-1-ylbenzenecolorless

There total 26 articles about (E)-undec-1-en-1-ylbenzenecolorless which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane (5123-13-7) + undec-1-enal dimethyl acetal (75456-63-2) → (E)-undec-1-en-1-ylbenzenecolorless (107224-27-1)

Guidance literature:

With bis(acetylacetonate)nickel(II); diisobutylaluminium hydride; tricyclohexylphosphine; In hexane; toluene; at 90 ℃; for 12h; diastereoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.9b00946

Reference yield: 79.0%

O-phenyl O-(1-phenylundecyl) carbonothioate (1424273-59-5) → undecylbenzene (6742-54-7) + (E)-undec-1-en-1-ylbenzenecolorless (107224-27-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; at 90 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2013.01.030

Reference yield: 75.0%

iodobenzene (591-50-4) + undec-1-enal dimethyl acetal (75456-63-2) → (E)-undec-1-en-1-ylbenzenecolorless (107224-27-1)

Guidance literature:

undec-1-enal dimethyl acetal; With n-butyllithium; zirconocene dichloride; In tetrahydrofuran; at -78 - 20 ℃;

iodobenzene; With copper(l) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 50 ℃; for 3h; Further stages.;

DOI:10.1021/jo005561n

upstream raw materials:

1-phenylundecan-1-ol

α-decyldibenzyl ketone

1-bromo dodecane

benzaldehyde

Downstream raw materials:

1-bromo-11-phenylundecane

1,14-Diphenyl-tetradecadien-(1,3)

11-phenylundecylalcohol