1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene

Base Information

• Chemical Name: 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene
• CAS No.: 16030-08-3
• Molecular Formula: C₂₉H₂₃ClSi
• Molecular Weight: 435.04
• Mol file: 16030-08-3.mol

Synonyms:1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene

Chemical Property of 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene

There total 1 articles about 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methyltrichlorosilane (75-79-6) + diphenyl acetylene (501-65-5) → 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene (16030-08-3)

Guidance literature:

Multistep reaction; (i) Li, (ii) THF, /BRN= 1361381/;

DOI:10.1021/ja01050a013

Reference yield: 90.0%

1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene (16030-08-3) → 1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene) (102632-49-5)

Guidance literature:

With sodium; In tetrahydrofuran; at 20 ℃; for 10h; Inert atmosphere;

DOI:10.3390/molecules16108451

Reference yield: 70.0%

cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + 1-chloro-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene (16030-08-3) → (1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadienyl)cyclopentadienyldicarbonyliron (105311-74-8)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; (CpFe(CO)2)2 stirred with Na amalgam in THF for 1.5 h under N2, added to a THF soln. of silacyclopentadiene, mixt. stirred for 1.5 h; hexane added, filtration, solvent evapd., residue crystd. from toluene-hexane; elem. anal.;

DOI:10.1021/om00144a025

upstream raw materials:

Methyltrichlorosilane

diphenyl acetylene

Downstream raw materials:

dimethyl-(1-methyl-2,3,4,5-tetraphenyl-1H-silol-1-yl)-amine

bis(methyltetraphenyl)silole siloxane

1-hydroxy-1-methyl-2,3,4,5-tetraphenylsilole

1-hydrido-1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene