CYCLOPENTADIENYLIRON DICARBONYL DIMER

Base Information

• Chemical Name: CYCLOPENTADIENYLIRON DICARBONYL DIMER
• CAS No.: 38117-54-3
• Molecular Formula: C14H10 Fe2 O4
• Molecular Weight: 353.925
• Mol file: 38117-54-3.mol

Synonyms:Iron,tetracarbonyldi-p-cyclopentadienyldi-(8CI); Bis(dicarbonyl(h5-cyclopentadienyl)iron)

Chemical Property of CYCLOPENTADIENYLIRON DICARBONYL DIMER

Chemical Property:

• Melting Point: 194 °C (dec.)(lit.)
• PSA: 0.00000
• LogP: 1.20600

Purity/Quality:

99.90% ^*data from raw suppliers

Cyclopentadienyliron Dicarbonyl Dimer ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/22
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of CYCLOPENTADIENYLIRON DICARBONYL DIMER

There total 756 articles about CYCLOPENTADIENYLIRON DICARBONYL DIMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) + [(η(5)-cyclopentadienyl)Fe(CO)(P(OPh)3)(Cl)] → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + bis(phenylthio)methane (3561-67-9) + 1,2-bis(phenylthio)ethane (622-20-8) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

In tetrahydrofuran; mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;

DOI:10.1016/S0022-328X(00)86902-8

Reference yield: 94.0%

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) + [(C5H5)Fe(CO)2P(C6H5)3](1+)*Cl(1-)=[(C5H5)Fe(CO)2P(C6H5)3]Cl (12100-38-8) → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + bis(phenylthio)methane (3561-67-9) + 1,2-bis(phenylthio)ethane (622-20-8) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

In tetrahydrofuran; mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;

DOI:10.1016/S0022-328X(00)86902-8

Reference yield: 92.0%

dicarbonyl(cyclopentadienyl)iron(II) chloride (12107-04-9) + [C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + bis(phenylthio)methane (3561-67-9) + 1,2-bis(phenylthio)ethane (622-20-8) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

In tetrahydrofuran; mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;

DOI:10.1016/S0022-328X(00)86902-8

upstream raw materials:

dicarbonyl(cyclopentadienyl)iron(II) chloride

copper

benzyl chloride

benzene

Downstream raw materials:

[Fe(C₅H₅)(C₆₀(CH₂C₆H₅)5)]

dicarbonylcyclopentadienyliodoiron(II)

iron pentacarbonyl

cobaltocene

Refernces

• 1、 Sartain, William J.,Selegue, John P.. "Synthesis and structure of [(NMe2)3TiFe(CO)2(Cp)]: A stable iron-titanium bond". . p. 1812 - 1815. Retrieved 1987.
• 2、 Campbell, Michel J. M.,Morrison, Elizabeth,Rogers, Vernon,Baker, Paul K.,Povey, David C.,Smith, Gallienus W.. "". . p. 2371 - 2378. Retrieved 1989.
• 3、 Bassi, Marco,Carlucci, Lucia,Zanotti, Valerio. "". . p. 171 - 174. Retrieved 1993.
• 4、 Bonnesen, Peter V.,Baker, Anthony T.,Hersh, William H.. "". . p. 8304 - 8305. Retrieved 1986.
• 5、 Cooke, Michael,Forrow, Nigel J.,Knox, Selby A. R.. "Organic Chemistry of Dinuclear Metal Centres. Part 5. Generation of Hydrocarbons from Methylene Chains linking Two Metal Centres. Evidence for a Dimetallacycle Intermediate". . p. 2435 - 2440. Retrieved 1983.
• 6、 Gracey, Benjamin,Knox, Selby A. R.,Macpherson, Kirsty A.,Orpen, Guy A.,Stobart, Stephen. "Organic chemistry of Dinuclear Metal Centres. Part 8. Organo-Iron-Ruthenium Chemistry. X-Ray Structure of trans-". . p. 1935 - 1944. Retrieved 1985.
• 7、 Butler, Ian R.,Cullen, William R.,Lindsell, W. Edward,Preston, Peter N.,Rettig, Steven J.. "The Reaction of Acetylenes with Compounds containing Fe-Aryl Bonds. A Convenient and Novel Synthesis of Indenones". . p. 439 - 441. Retrieved 1987.
• 8、 Webster, Charles Edwin,Fan, Yubo,Hall, Michael B.,Kunz, Doris,Hartwig, John F.. "Experimental and computational evidence for a boron-assisted, σ-bond metathesis pathway for alkane borylation". . p. 858 - 859. Retrieved 2003.
• 9、 Belousov, Yuri A.,Kondrasenko, Alexander A.,Semeikin, Oleg V.,Ustynyuk, Nikolai A.,Vasiliev, Alexander D.,Verpekin, Victor V.. "Catalyzed M-C coupling reactions in the synthesis of s-(pyridylethynyl)dicarbonylcyclopentadienyliron complexes". . p. 17014 - 17025. Retrieved 2020.
• 10、 Aldridge,Calder,Baghurst,Light,Hursthouse. "Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands". . p. 9 - 14. Retrieved 2002.