Cp*RhCl(Ph)(PMe₃)

Base Information

• Chemical Name: Cp*RhCl(Ph)(PMe₃)
• CAS No.: 88704-28-3
• Molecular Formula: C₁₉H₂₉ClPRh
• Molecular Weight: 426.772
• Mol file: 88704-28-3.mol

Synonyms:Cp*RhCl(Ph)(PMe₃)

Chemical Property of Cp*RhCl(Ph)(PMe₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Cp*RhCl(Ph)(PMe₃)

There total 2 articles about Cp*RhCl(Ph)(PMe₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

(C5Me5)Rh(PMe3)(H)2 (84624-03-3) → (η5-pentamethylcyclopentadienyl)Rh(trimethylphosphine)Cl2 + Cp*RhCl(Ph)(PMe3) (88704-28-3) + (C5(CH3)5)Rh(P(CH3)3)(C5H9)Cl

Guidance literature:

With tetrachloromethane; Cyclopentane; benzene; In tetrahydrofuran; Irradiation (UV/VIS); 20 min, from -30°C to -40°C, -40°C, under N2; volatiles removed at 25°C;

DOI:10.1021/ja00318a018

Reference yield:

(C5Me5)Rh(PMe3)(H)2 (84624-03-3) + benzene-d6 (1076-43-3) → Cp*RhCl(Ph)(PMe3) (88704-28-3) + (C5(CH3)5)Rh(P(CH3)3)(C6(2)H5)Cl

Guidance literature:

With tetrachloromethane; benzene; In tetrachloromethane; benzene-d6; benzene; Irradiation (UV/VIS); photolysis (C5Me5)Rh(PMe3)H2 in mixt. 1:1 (v/v) C6H6/C6D6 at 10°C for 5 min, to resulting mixt. (C5Me5)Rh(PMe3)(C6H5)H and (C5Me5)Rh(PMe3)(C6D5)D CCl4 added; solvent removed on vac. line, residue chromed on thick-layer SiO2 platewith CH2Cl2 as eluent;

DOI:10.1021/ja00276a019

Reference yield: 85.0%

Cp*RhCl(Ph)(PMe3) (88704-28-3) → [Rh(H)(Ph)(η5-pentamethylcyclopentadienyl)(PMe3)] (81971-46-2)

Guidance literature:

With Na(+){H₂Al(OCH₂CH₂OCH₃)2}(-); In tetrahydrofuran; toluene; under N2; flash chromatographed, evaporated;

DOI:10.1021/ja00318a018

upstream raw materials:

(C₅Me₅)Rh(PMe₃)(H)2

benzene-d6

Downstream raw materials:

[Rh(H)(Ph)(η5-pentamethylcyclopentadienyl)(PMe3)]

(C₅(CH₃)5)Rh(P(CH₃)3)(SO₂C₆H₅)(Cl)

[Cp(*)Rh(Ph)(PMe₃)ClCH₂Cl]BAr'4