2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

Base Information

Chemical Name:2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene
CAS No.:111154-42-8
Molecular Formula:C₂₀H₁₇NO₅
Molecular Weight:351.359
Hs Code.:

Synonyms:2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

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Chemical Property of 2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

Chemical Property:

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Technology Process of 2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

There total 4 articles about 2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.7%

: 111154-34-8
2-(4-isopropoxy-3-methoxyphenyl)-6,7-methylendioxy-1-(N-methylformamido)naphthalene

: 111154-42-8
2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

Guidance literature:: With sulfuric acid; In acetic acid; at 100 ℃; for 1h;
DOI:10.1248/cpb.35.2717

Reference yield:

: 115439-10-6
2-(4'-isopropoxy-3'-methoxyphenyl)-6,7-methylenedioxy-3,4-dihydronaphtalen-1(2H)-one

: 111154-42-8
2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) titanium tetrachloride (TiCl₄); 2.) sodium borohydride (NaBH₄) / 1.) CHCl₃, room temp., 2 h, reflux, 30 min; 2.) MeOH, room temp.

2: 89.9 percent / CHCl₃ / 6 h / Heating

3: 89.9 percent / 2,3- dichloro-5,6-dicyano-p-benzoquinone (DDQ) / benzene / 1 h / Heating

4: 76.7 percent / cc. sulfuric acid (H₂SO₄) / acetic acid / 1 h / 100 °C

With sodium tetrahydroborate; sulfuric acid; titanium tetrachloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; acetic acid; benzene;
DOI:10.1248/cpb.35.2717

Reference yield:

: 111154-30-4,115522-72-0
cis-N-methyl-2-(4-isopropoxy-3-methoxyphenyl)-6,7-methylenedioxy-1,2,3,4-tetrahydro-1-naphthylamine

: 111154-42-8
2-(4-hydroxy-3-methoxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: 89.9 percent / CHCl₃ / 6 h / Heating

2: 89.9 percent / 2,3- dichloro-5,6-dicyano-p-benzoquinone (DDQ) / benzene / 1 h / Heating

3: 76.7 percent / cc. sulfuric acid (H₂SO₄) / acetic acid / 1 h / 100 °C

With sulfuric acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; acetic acid; benzene;
DOI:10.1248/cpb.35.2717