(1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene

Base Information

• Chemical Name: (1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene
• CAS No.: 868979-60-6
• Molecular Formula: C₂₃H₂₅BrO₂
• Molecular Weight: 413.354

Synonyms:(1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene

Chemical Property of (1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene

Chemical Property:

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Technology Process of (1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene

There total 1 articles about (1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3R,4R)-12-bromo-6-methoxyethoxy-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene + methylmagnesium bromide (75-16-1) → (1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene (868979-60-6)

Guidance literature:

In toluene; at 20 ℃; for 12h;

DOI:10.1248/cpb.53.952

Reference yield: 86.0%

(1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene (868979-60-6) → (1R,2R,6S)-2-bromo-6-[(2S)-2-hydroxypropyl]cyclohexanol

Guidance literature:

With hydrogen; palladium dihydroxide; In tetrahydrofuran; ethanol; at 20 ℃;

DOI:10.1248/cpb.53.952

Reference yield: 85.0%

(1R,3R,4R,6S,8R,12R)-12-bromo-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodec-9-ene (868979-60-6) → (1R,3R,4R,6S,8R,9S,10R,12R)-12-bromo-9,10-dihydroxy-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodecane + (1R,3R,4R,6S,8R,9R,10S,12R)-12-bromo-9,10-dihydroxy-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodecane (868979-66-2)

Guidance literature:

With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In acetone; at 20 ℃; for 1.5h;

DOI:10.1248/cpb.53.952

upstream raw materials:

methylmagnesium bromide

Downstream raw materials:

(1R,3R,4R,6S,8R,9R,10S,12R)-12-bromo-9,10-dihydroxy-6-methyl-2,5-dioxa-3,4-diphenylbicyclo[6.4.0]-dodecane

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