[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

Base Information

Chemical Name:[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride
CAS No.:85744-68-9
Molecular Formula:C₃₄H₃₃ClP₃Pd*Cl
Molecular Weight:711.883
Hs Code.:

Synonyms:[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

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Chemical Property of [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

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Technology Process of [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

There total 5 articles about [chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: palladium dichloride

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 85744-68-9
[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

Guidance literature:: With NaCl; In dichloromethane; water; heating PdCl2 and NaCl in H2O to 80°C until a clear soln. is obtained, cooling to room temp., addn. of ligand in CH2Cl2, stirring (room temp., 1 h); solvent removal (vac.), filtration, washing (H2O), drying (vac.), recrystn. (CH2Cl2/n-hexane); elem. anal.;
DOI:10.1039/a903775f

Reference yield: 68.0%

: 10025-98-6
potassium tetrachloropalladate(II)

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 85744-68-9
[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

Guidance literature:: In dichloromethane; water; a soln. of P compd. (CH2Cl2) added dropwise to a soln. of Pd compd. (H2O, 1 equiv.), stirred for 1-24 h at room temp.; concd. (vac.), diethyl ether added, ppt. filtered, washed (H2O), dried vac.), recrystd. (CH2Cl2/hexane), dried (vac.); elem. anal.;
DOI:10.1016/j.ica.2005.03.018

Reference yield: 67.0%

: 7647-14-5
sodium chloride

: palladium dichloride

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 85744-68-9
[chloro(bis[(2-diphenylphosphino)ethyl]phenylphosphine)palladium(II)] chloride

Guidance literature:: In dichloromethane; water; suspn. of PdCl2, NaCl in H2O was heated in water bath, cooled to ambienttemp., ligand in CH2Cl2 was added dropwise, stirred for 1 h at room tem p.; solvent was removed in vacuo, filtered off, washed with water, dried in vacuo, recrystd,. from CH2Cl2-n-hexane; elem. anal.;
DOI:10.1016/S0020-1693(00)00329-7