(R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether

Base Information

• Chemical Name: (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether
• CAS No.: 87106-22-7
• Molecular Formula: C₁₇H₂₆O₂
• Molecular Weight: 262.392
• Mol file: 87106-22-7.mol

Synonyms:(R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether

Chemical Property of (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether

There total 2 articles about (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

→ (S,E)-8-(benzyloxy)-2,6-dimethyl-3-octen-2-ol (161905-08-4) + (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether (87106-22-7)

Guidance literature:

With diphenyl diselenide; tetraethylammonium bromide; In acetonitrile; Title compound not separated from byproducts; Ambient temperature; electrolysis (7.6 F/mol);

DOI:10.1021/jo00196a046

Reference yield:

(R)-(+)-citronellyl benzyl ether (83541-12-2) → (R,E)-(+)-7-hydroxy-3,7-dimethyl-5-octenyl benzyl ether (87106-22-7)

Guidance literature:

With tert.-butylhydroperoxide; diphenyl diselenide; magnesium sulfate; Yield given. Multistep reaction; 1.) CH₂Cl₂, 20 h, room temperature, 2.) room temperature, overnight;

DOI:10.1016/S0040-4020(01)91971-4

Reference yield: 89.0%

8-(Benzyloxy)-2,6-dimethyloct-3-en-2-ol (87106-22-7,92142-15-9,96154-41-5) → (3R)-3,7-Dimethyl-4,6-octadienyl Benzyl Ether (92056-73-0,92056-74-1,96154-42-6,96193-65-6,96193-66-7) + (3S)-3,7-Dimethyl-4,6-octadienyl Benzyl Ether (92056-73-0,92056-74-1,96154-42-6,96193-65-6,96193-66-7)

Guidance literature:

With perchloric acid; In tetrahydrofuran; at 60 - 65 ℃; for 1h; Title compound not separated from byproducts; also with BF₃ etherate and 60percent H₂SO₄;

DOI:10.1021/jo00196a046

upstream raw materials:

(R)-(+)-citronellyl benzyl ether

Downstream raw materials:

(3R)-3,7-Dimethyl-4,6-octadienyl Benzyl Ether

(3S)-3,7-Dimethyl-4,6-octadienyl Benzyl Ether

(R)-(-)-3-methyl-1,5-pentanediol monobenzyl ether

(S)-1-(benzyloxy)-5-iodo-3-methylpentane