161905-08-4Relevant academic research and scientific papers
A concise stereoselective formal total synthesis of the cytotoxic macrolide (+)-Neopeltolide via Prins cyclization
Yadav, Jhillu Singh,Krishana, Gunda Gopala,Kumar, Satya Narayana
experimental part, p. 480 - 487 (2010/03/03)
A convergent and highly stereoselective formal total synthesis of the naturally occurring, cytotoxic 14-membered macrolide neopeltolide has been achieved via two Prins cyclizations.
Pheromone Synthesis, CLXVII. - Synthesis of All of the Eight Stereoisomers of Methyl 2,6,10-Trimethyltridecanoate, the Male-produced Pheromone of the Stink Bugs, Euschistus heros and E. obscurus
Mori, Kenji,Murata, Noriaki
, p. 1153 - 1160 (2007/10/02)
All of the eight possible stereoisomers of methyl 2,6,10-trimethyltridecanoate (1), the male-produced attractant pheromone of the South American soybean pest, Euschistus heros, and that of E. obscurus, are synthesized by starting from the enantiomers of citronellol (2) and methyl 3-hydroxy-2-methylpropanoate (9). - Key Words: Euschistus heros / Euschistus obscurus / Pheromones / Stink bugs / Sulfones, alkylation of / Tridecanoate, methyl 2,6,10-trimethyl-
