C₄₉H₆₁IO₁₃

Base Information

• Chemical Name: C₄₉H₆₁IO₁₃
• CAS No.: 1425471-94-8
• Molecular Formula: C₄₉H₆₁IO₁₃
• Molecular Weight: 984.92
• Mol file: 1425471-94-8.mol

Synonyms:C₄₉H₆₁IO₁₃

Chemical Property of C₄₉H₆₁IO₁₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₉H₆₁IO₁₃

There total 1 articles about C₄₉H₆₁IO₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

C47H57IO13 (1425471-91-5) + methyl iodide (74-88-4) → C49H61IO13 (1425471-94-8)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 16h;

DOI:10.1002/anie.201206221

Reference yield: 88.0%

1-chloro-5-hexyne (10297-06-0) + C49H61IO13 (1425471-94-8) → (6-(4-hydroxyphenyl)-1-chloro-5-hexyne)-yl (2,3,4-tri-O-methyl-α-L-fucopyranosyl)-(1→3)-(2,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-(4-O-benzyl-2-O-methyl)-α-L-rhamnopyranoside

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine; at 40 ℃; for 2h;

DOI:10.1016/j.ejmech.2017.03.058

Reference yield: 51.0%

C49H61IO13 (1425471-94-8) + (3R,4S,9R,11R)-3-methoxy-4-methylheptacos-26-yne-9,11-diol (1425471-39-1) → C78H116O16 (1425471-97-1)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine; at 40 ℃; for 1.5h;

DOI:10.1002/anie.201206221

upstream raw materials:

C₄₇H₅₇IO₁₃

methyl iodide

Downstream raw materials:

C₇₈H₁₁₆O₁₆

Refernces

• 1、 Barroso, Santiago,Castelli, Riccardo,Baggelaar, Marc P.,Geerdink, Danny,Terhorst, Bjorn,Casas-Arce, Eva,Overkleeft, Herman S.,Van Der Marel, Gijsbert A.,Codée, Jeroen D.C.,Minnaard, Adriaan J.. "Total synthesis of the triglycosyl phenolic glycolipid PGL-tb1 from mycobacterium tuberculosis". supporting information. p. 11774 - 11777. Retrieved 2013/01/15.