(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

Base Information

Chemical Name:(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine
CAS No.:914359-86-7
Molecular Formula:C₂₉H₃₉NO₂Se
Molecular Weight:512.594
Hs Code.:

Synonyms:(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

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Chemical Property of (1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

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Technology Process of (1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

There total 3 articles about (1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 914359-71-0
(S)-[(2S,4aS,7R,8aR)-3-(3-methylbut-2-enyl)-4,4,7-trimethyl-octahydro-2H-benzo[e][1,3]oxazin-2-yl](phenyl)methanol

: 5707-04-0
Phenylselenyl chloride

: 914359-86-7
(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

: 914359-84-5
(1S,3S,6aS,9R,10aR,11aS)-1-phenyl-3-(1-methyl-1-phenylselenenylethyl)-6,6,9-trimethyl-decahydro-3H,7H-[1,4]oxazino[3,4-b][1,3]benzoxazine

Guidance literature:: Phenylselenyl chloride; With tin(IV) chloride; In dichloromethane; at -78 ℃; for 0.333333h;

(S)-[(2S,4aS,7R,8aR)-3-(3-methylbut-2-enyl)-4,4,7-trimethyl-octahydro-2H-benzo[e][1,3]oxazin-2-yl](phenyl)methanol; In dichloromethane; at -78 ℃; for 2h;
DOI:10.1021/jo061547k

Reference yield:

: 914359-71-0
(S)-[(2S,4aS,7R,8aR)-3-(3-methylbut-2-enyl)-4,4,7-trimethyl-octahydro-2H-benzo[e][1,3]oxazin-2-yl](phenyl)methanol

: 5707-04-0
Phenylselenyl chloride

: 914359-86-7
(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

: (1S,4R,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

: (1S,3R,6aS,9R,10aR,11aS)-1-phenyl-3-(1-methyl-1-phenylselenenylethyl)-6,6,9-trimethyl-decahydro-3H,7H-[1,4]oxazino[3,4-b][1,3]benzoxazine

: 914359-84-5
(1S,3S,6aS,9R,10aR,11aS)-1-phenyl-3-(1-methyl-1-phenylselenenylethyl)-6,6,9-trimethyl-decahydro-3H,7H-[1,4]oxazino[3,4-b][1,3]benzoxazine

Guidance literature:: With potassium carbonate; In dichloromethane; at 0 ℃; for 5h;
DOI:10.1021/jo061547k

Reference yield:

: 503004-89-5
(2S,4aS,7R,8aR)-phenyl-[4,4,7-trimethyl-3-(3-methylbut-2-enyl)octahydrobenzo[e][1,3]oxazin-2-yl] ketone

: 914359-86-7
(1S,4S,7aS,10R,11aR,12aS)-1-phenyl-4-phenylselenenyl-3,3,7,7,10-pentamethyl-decahydro-3H,7H-[1,4]oxazepino[3,4-b][1,3]benzoxazine

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / NaBH₄ / ethanol / 5 h / -10 - 0 °C

2: K₂CO₃ / CH₂Cl₂ / 5 h / 0 °C

With sodium tetrahydroborate; potassium carbonate; In ethanol; dichloromethane;
DOI:10.1021/jo061547k