dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II)

Base Information

• Chemical Name: dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II)
• CAS No.: 1334313-25-5
• Molecular Formula: C₂₇H₂₄Cl₂NPPt
• Molecular Weight: 659.454
• Mol file: 1334313-25-5.mol

Synonyms:dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II)

Chemical Property of dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II)

There total 2 articles about dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

N-(2,6-dimethylphenyl)-1-[2-(diphenylphosphanyl)phenyl]methanimine + dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) → dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II) (1334313-25-5)

Guidance literature:

In dichloromethane; at 20 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jinorgbio.2013.09.010

Reference yield:

(2-formylphenyl)(diphenyl)phosphine (50777-76-9) → dichloro[(2-diphenylphosphinobenzylidene)-2,6-dimethylphenylenamine] platinum(II) (1334313-25-5)

Guidance literature:

Multi-step reaction with 2 steps

1: magnesium sulfate / dichloromethane / 20 °C / Inert atmosphere; Schlenk technique

2: dichloromethane / 6 h / 20 °C / Inert atmosphere; Schlenk technique

With magnesium sulfate; In dichloromethane; 1: |Schiff Reaction;

DOI:10.1016/j.jinorgbio.2013.09.010

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

(2-formylphenyl)(diphenyl)phosphine