Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane

Base Information

• Chemical Name: Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane
• CAS No.: 3528-12-9
• Molecular Formula: C10H24 Si2
• Molecular Weight: 200.472
• Mol file: 3528-12-9.mol

Synonyms:2,7-Disilaoct-4-ene,2,2,7,7-tetramethyl- (6CI,7CI); Silane, 2-butene-1,4-diylbis[trimethyl- (9CI);Silane, 2-butenylenebis[trimethyl- (8CI); 1,4-Bis(trimethylsilyl)-2-butene

Chemical Property of Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane

Chemical Property:

• PSA: 0.00000
• LogP: 4.21900

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane

There total 14 articles about Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + allyl-trimethyl-silane (762-72-1) → 1,4-bis(trimethylsilyl)2-butene (3528-12-9) + (E)-trimethyl(3-phenylallyl)silane (40595-34-4)

Guidance literature:

With triphenylphosphine; Mo(CHCMe2Ph)(NAr)2 (Schrock's molybdenum catalyst); In diethyl ether; for 4h; Yields of byproduct given;

DOI:10.1016/0040-4039(96)00230-4

Reference yield: 89.0%

1-ethenyl-4-methylbenzene (622-97-9,24936-41-2) + allyl-trimethyl-silane (762-72-1) → 1,4-bis(trimethylsilyl)2-butene (3528-12-9) + trimethyl<3-(4-methylphenyl)-2-propenyl>silane (111133-19-8)

Guidance literature:

Mo(CHCMe2Ph)(NAr)2 (Schrock's molybdenum catalyst); In 1,2-dimethoxyethane; Yields of byproduct given;

DOI:10.1016/0040-4039(96)00230-4

Reference yield: 80.0%

buta-1,3-dien-1-ylbenzene (1515-78-2) + allyl-trimethyl-silane (762-72-1) → 1,4-bis(trimethylsilyl)2-butene (3528-12-9) + Trimethyl-((2E,4E)-5-phenyl-penta-2,4-dienyl)-silane

Guidance literature:

Mo(CHCMe2Ph)(NAr)2 (Schrock's molybdenum catalyst); In 1,2-dimethoxyethane; for 4h; Yields of byproduct given;

DOI:10.1016/0040-4039(96)00230-4

upstream raw materials:

1-hexene

allyl-trimethyl-silane

(Z)-pent-2-ene

styrene

Downstream raw materials:

1-Phenyl-2-trimethylsilanylmethyl-but-3-en-1-one