1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

Base Information

Chemical Name:1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone
CAS No.:1448160-10-8
Molecular Formula:C₃₁H₃₆O₁₀S₂
Molecular Weight:632.753
Hs Code.:

Synonyms:1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

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Chemical Property of 1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

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Technology Process of 1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

There total 1 articles about 1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1073478-35-9
1-C-(6'-O-acetyl-3',4'-di-O-benzyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

: 124-63-0
methanesulfonyl chloride

: 1448160-10-8
1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

Guidance literature:: 1-C-(6'-O-acetyl-3',4'-di-O-benzyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone; With diethylamine; In methanol; at 20 ℃;

methanesulfonyl chloride; With triethylamine; In dichloromethane; at 0 - 20 ℃; for 8h;
DOI:10.1039/c3cc42292e

Reference yield: 80.0%

: 1448160-10-8
1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

: 1448160-12-0
C₂₄H₂₈O₇S

Guidance literature:: With potassium carbonate; In dimethyl sulfoxide; at 50 ℃; for 5h;
DOI:10.1039/c3cc42292e

Reference yield:

: 1448160-10-8
1-C-(3',4'-di-O-benzyl-6'-O-methylsulfonyl-2'-O-tosyl-α-D-mannopyranosyl)-acetone

: 1448160-28-8
(2S,3aR,4R,5S,6R,7aR)-2-allyl-4,5-bis(benzyloxy)-6-[(methanesulfonyloxy)methyl]2-methylhexahydro-furo[2,3-b]pyran

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / dimethyl sulfoxide / 5 h / 50 °C

2: bismuth(III) chloride / toluene / -40 - 20 °C / Inert atmosphere

With bismuth(III) chloride; potassium carbonate; In dimethyl sulfoxide; toluene;
DOI:10.1039/c3cc42292e