DICHLORO(BENZENE)RUTHENIUM(LL) DIMER

Base Information

• Chemical Name: DICHLORO(BENZENE)RUTHENIUM(LL) DIMER
• CAS No.: 35796-48-6
• Molecular Formula: C6H6 Cl2 Ru
• Molecular Weight: 250.09
• Mol file: 35796-48-6.mol

Synonyms:Benzene,ruthenium complex; Dichloro(benzene)ruthenium

Chemical Property of DICHLORO(BENZENE)RUTHENIUM(LL) DIMER

Chemical Property:

• PSA: 0.00000
• LogP: 3.40580

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DICHLORO(BENZENE)RUTHENIUM(LL) DIMER

There total 1 articles about DICHLORO(BENZENE)RUTHENIUM(LL) DIMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

cyclohexa-1,4-diene (1165952-92-0) + ruthenium(III) chloride trihydrate → [(η6-C6H6)RuCl2] (35796-48-6)

Guidance literature:

In ethanol; for 48h; Reflux;

DOI:10.1021/ic502051y

Reference yield: 90.7%

[(η6-C6H6)RuCl2] (35796-48-6) + 2-(2-chlorophenyl)imidazo<4,5-f>1,10-phenanthroline (215601-93-7) → [(η6-C6H6)Ru(2-(2-chlorophenyl)-1H-imidazo[4,5f][1,10]phenanthroline)Cl]Cl (1491936-54-9)

Guidance literature:

In dichloromethane; at 60 ℃; for 0.5h; Reflux; Microwave irradiation;

DOI:10.1071/CH13269

Reference yield: 86.0%

[(η6-C6H6)RuCl2] (35796-48-6) + sodium acetate (127-09-3) + (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,98327-87-8,136655-44-2) → bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II) (325146-81-4,104713-03-3,114818-52-9,104621-48-9,261948-85-0)

Guidance literature:

[(η6-C6H6)RuCl2]; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In N,N-dimethyl-formamide; at 100 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

sodium acetate; In methanol; N,N-dimethyl-formamide; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201809719

upstream raw materials:

cyclohexa-1,4-diene

Downstream raw materials:

[(η⁶-C₆H₆)Ru(2-(2-chlorophenyl)-1H-imidazo[4,5f][1,10]phenanthroline)Cl]Cl

Ru[(S)-SegPhos](OAc)₂

bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II)

Ru(OAc)₂(S)-DM-SegPhos