1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

Base Information

Chemical Name:1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate
CAS No.:88035-79-4
Molecular Formula:C₂₉H₄₀O₂Si
Molecular Weight:448.721
Hs Code.:

Synonyms:1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

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Chemical Property of 1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

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Technology Process of 1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

There total 3 articles about 1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 2216-51-5
(-)-menthol

: (1S,3S)-2,2-Diphenyl-3-trimethylsilanyl-cyclopropanecarbonyl chloride

: 88035-79-4
1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

Guidance literature:: In diethyl ether; for 1.5h; Heating;
DOI:10.1021/ja00314a014

Reference yield:

: 88035-83-0
trans-Methyl-2.2-diphenyl-3-trimethylsilylcyclopropancarboxylat

: 88035-79-4
1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 24 percent / KOH / ethanol / 1.3 h / Heating

2: thionyl chloride / 2 h / Heating

3: 55 percent / diethyl ether / 1.5 h / Heating

With potassium hydroxide; thionyl chloride; In diethyl ether; ethanol;
DOI:10.1021/ja00314a014

Reference yield:

: 88082-51-3
trans-2,2-diphenyl-3-(trimethylsilyl)-cyclopropanecarboxylic acid

: 88035-79-4
1-menthyl (+)-1(S)-3-(S)-2,2-diphenyl-3-(trimethylsilyl)cyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: thionyl chloride / 2 h / Heating

2: 55 percent / diethyl ether / 1.5 h / Heating

With thionyl chloride; In diethyl ether;
DOI:10.1021/ja00314a014