4-Fluoro-3-methylbenzyl bromide

Base Information

Chemical Name:4-Fluoro-3-methylbenzyl bromide
CAS No.:261951-70-6
Molecular Formula:C8H8 Br F
Molecular Weight:203.054
Hs Code.:2903999090
European Community (EC) Number:670-722-4
DSSTox Substance ID:DTXSID20380790
Wikidata:Q82171240
Mol file:261951-70-6.mol

Synonyms:4-Fluoro-3-methylbenzyl bromide;261951-70-6;4-(bromomethyl)-1-fluoro-2-methylbenzene;Benzene, 4-(bromomethyl)-1-fluoro-2-methyl-;SCHEMBL177531;DTXSID20380790;ZZGGOSDHWXCOCA-UHFFFAOYSA-N;MFCD01631425;AKOS009158363;4-fluoro-3-methylbenzyl bromide, 97%;4-bromomethyl-1-fluoro-2-methyl-benzene;PS-10042;4-Fluoro-3-methylbenzyl bromide, AldrichCPR;FT-0644156;D87871;EN300-1232078

Suppliers and Price of 4-Fluoro-3-methylbenzyl bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Fluoro-3-methylbenzylBromide
50mg
$ 45.00

SynQuest Laboratories
4-Fluoro-3-methylbenzyl bromide
10 g
$ 311.00

SynQuest Laboratories
4-Fluoro-3-methylbenzyl bromide
5 g
$ 175.00

SynQuest Laboratories
4-Fluoro-3-methylbenzyl bromide
1 g
$ 39.00

Oakwood
4-Fluoro-3-methylbenzylbromide 97%
250mg
$ 20.00

Oakwood
4-Fluoro-3-methylbenzylbromide 97%
1g
$ 40.00

Matrix Scientific
4-Fluoro-3-methylbenzyl bromide
5g
$ 133.00

Matrix Scientific
4-Fluoro-3-methylbenzyl bromide
1g
$ 29.00

Chemenu
4-Fluoro-3-methylbenzylbromide 95%+
5g
$ 789.00

American Custom Chemicals Corporation
4-FLUORO-3-METHYLBENZYL BROMIDE 95.00%
1G
$ 611.00

Total 26 raw suppliers

Chemical Property of 4-Fluoro-3-methylbenzyl bromide

Chemical Property:

Vapor Pressure:0.207mmHg at 25°C
Refractive Index:1.539
Boiling Point:216.3°Cat760mmHg
Flash Point:87.4°C
PSA：0.00000
Density:1.456g/cm³
LogP:3.02900
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Water Solubility.:Insoluble in water.
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:201.97934
Heavy Atom Count:10
Complexity:105

Purity/Quality:

97% ^*data from raw suppliers

4-Fluoro-3-methylbenzylBromide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C=CC(=C1)CBr)F
Uses Pharmaceutical Intermediate. Organic synthesis, tear gas mixture of ortho-, meta-, and para-isomers.

Technology Process of 4-Fluoro-3-methylbenzyl bromide

There total 1 articles about 4-Fluoro-3-methylbenzyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 261951-66-0
4-fluoro-3-methylbenzyl alcohol

: 261951-70-6
4-(bromomethyl)-1-fluoro-2-methylbenzene

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; for 1h;

Reference yield: 100.0%

: 261951-70-6
4-(bromomethyl)-1-fluoro-2-methylbenzene

: methyl 5-(4-fluoro-2-methylphenyl)-1-oxo-1,2,3,4-tetrahydroisoquinoline-7-carboxylate

: methyl 5-(4-fluoro-2-methylphenyl)-2-(4-fluoro-3-methylbenzyl)-1-oxo-1,2,3,4-tetrahydroisoquinoline-7-carboxylate

Guidance literature:: methyl 5-(4-fluoro-2-methylphenyl)-1-oxo-1,2,3,4-tetrahydroisoquinoline-7-carboxylate; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.25h;

4-(bromomethyl)-1-fluoro-2-methylbenzene; In N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/acs.jmedchem.9b01608

Reference yield: 94.0%

: 502-44-3,24980-41-4,80137-66-2
hexahydro-2H-oxepin-2-one

: 261951-70-6
4-(bromomethyl)-1-fluoro-2-methylbenzene

: 1043453-91-3
6-(4-fluoro-3-methylbenzyloxy)hexanoic acid

Guidance literature:: hexahydro-2H-oxepin-2-one; 4-(bromomethyl)-1-fluoro-2-methylbenzene; With potassium hydroxide; In toluene; for 86h; Heating / reflux;

With hydrogenchloride; In water; at 20 ℃; pH=2;