trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

Base Information

Chemical Name:trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)
CAS No.:141997-65-1
Molecular Formula:C₃₂H₃₄Cl₂O₂P₂Ru
Molecular Weight:684.544
Hs Code.:

Synonyms:trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

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Chemical Property of trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

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Technology Process of trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

There total 1 articles about trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 142013-33-0
(oxetanyl-2-methyl)diphenylphosphine

: 141997-65-1
trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

Guidance literature:: In dichloromethane; addn. of the phosphine to a soln. of Ru(PPh3)3Cl2, stirring (Ar, 0.5 h, 20°C), the initially dark-brown suspn. changed to cherry-red; vol. reduced (vac.), addn. of hexane, solid filtered off (G4), washed (hexane), dried (vac.); elem. anal.; ratio of enantiomeric pairs = 1:3 (31P-NMR);

Reference yield: 73.0%

: 141997-65-1
trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

: 142012-47-3
carbonyl-trans-dichloro-trans-bis{(oxetane-2-ylmethyl)diphenylphosphine-P;O',P'}ruthenium(II)

Guidance literature:: With carbon monoxide; In dichloromethane; under Ar, bubbling CO through a soln. of Ru-compd. at room temp. for 5 min until the red soln. turned to orange; evapn. to low volume, pptn. upon addn. of n-hexane, filtration, washing three times (n-hexane), drying in vac., elem. anal.;

Reference yield: 73.0%

: 141997-65-1
trans-dichloro-cis-bis{(oxetane-2-ylmethyl)diphenylphosphine-O,P}ruthenium(II)

: 142012-47-3
carbonyl-trans-dichloro-trans-bis(oxetanyl-2-methyldiphenylphosphine-P;O,P)ruthenium(II)

Guidance literature:: With carbon monoxide; In dichloromethane; introduction of CO into a soln. of the complex (20°C), the initially red soln. changed to bright yellow; vol. reduced (vac.), addn. of hexane, solid filtered off (G4), washed (hexane), dried (vac.); elem. anal.; ratio of enantiomeric pairs = 1:3 (31P-NMR);