cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

Base Information

Chemical Name:cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron
CAS No.:72573-42-3
Molecular Formula:C₃₈H₃₂FeO₈P₂
Molecular Weight:734.462
Hs Code.:

Synonyms:cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

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Chemical Property of cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

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Technology Process of cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

There total 9 articles about cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 101-02-0
triphenyl phosphite

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 72573-42-3
cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

Guidance literature:: With potassium hydroxide; In tetrahydrofuran; water; byproducts: CO; (Ar); addn. of Fe(CO)5 to soln. of KOH; mixt. stirred for 0.5 h at 25°C; addn. of phosphite; reaction for 24 h;; org. solvent evapd. (reduced pressure); extn. (pentane); ext. concd.; cooled (-78°C, 3 h); solvent removed; dissolved (THF); concd.; pentane added; pptn. by cooling; ppt. washed (pentane) and dried (-20°C, reduced pressure); elem. anal.;

Reference yield: 90.0%

: Fe(CO)2{P(OC₆H₅)3}2(H)Si(C₆H₅)(CH₃)2

: 766-77-8
Dimethylphenylsilane

: 72573-42-3
cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

Guidance literature:: In benzene; byproducts: (C6H5(CH3)2Si)2, Fe(CO)3(P(OC6H5)3)2; (N2); keeping benzene soln. of Fe complex and 3-4-fold excess of dimethylphenylsilane at room temp. for 2 d; monitored by (1)H-NMR;

Reference yield: 89.0%

: 101-02-0
triphenyl phosphite

: 12002-28-7,22763-20-8,71564-37-9
cis-tetracarbonyldihydridoiron

: 72573-42-3
cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

Guidance literature:: In petroleum ether; byproducts: CO; stirred at 0°C for in absence of air for CO development, cooled to -80°C and stirred overnight, warmed to room temp., P(OPh)3 soln. in petroleum ether added, stirred for 30 min, cooled to -40°C,pptd.; filtered, recrystd. from petroleum ether at -40°C, elem. anal.;