(Hept-1-en-1-yl)di(propan-2-yl)silanol

Base Information

• Chemical Name: (Hept-1-en-1-yl)di(propan-2-yl)silanol
• CAS No.: 261717-41-3
• Molecular Formula: C13H28 O Si
• Molecular Weight: 228.45
• DSSTox Substance ID: DTXSID60697718
• Mol file: 261717-41-3.mol

Synonyms:DTXSID60697718;(Hept-1-en-1-yl)di(propan-2-yl)silanol

Chemical Property of (Hept-1-en-1-yl)di(propan-2-yl)silanol

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.448
• Boiling Point: 88°C/0.1mmHg
• PKA: 14.32±0.53(Predicted)
• Flash Point: 129.379°C
• PSA: 20.23000
• Density: 0.844g/cm³
• LogP: 4.41990
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 228.190942047
• Heavy Atom Count: 15
• Complexity: 177

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=C[Si](C(C)C)(C(C)C)O

Technology Process of (Hept-1-en-1-yl)di(propan-2-yl)silanol

There total 8 articles about (Hept-1-en-1-yl)di(propan-2-yl)silanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.3%

(E)-diisopropyl-(1-heptenyl)silyl chloride (261717-43-5) → (E)-(hept-1-enyl)diisopropylsilanol (261717-41-3)

Guidance literature:

With sodium hydrogencarbonate; In diethyl ether; water; at 20 ℃; for 0.5h;

DOI:10.1021/ol005565e

Reference yield: 80.0%

1-Heptyne (628-71-7) + chlorodiisopropylsilane (2227-29-4) → (E)-(hept-1-enyl)diisopropylsilanol (261717-41-3)

Guidance literature:

1-Heptyne; chlorodiisopropylsilane; With dihydrogen hexachloroplatinate;

With sodium hydrogencarbonate;

DOI:10.1021/ja037234d

Reference yield:

1-Iodonaphthalene (90-14-2) → (Z)-1-(1-heptenyl)naphthalene + (E)-(hept-1-enyl)diisopropylsilanol (261717-41-3)

Guidance literature:

With tetrabutyl ammonium fluoride; Pd(dba)2; In tetrahydrofuran;

upstream raw materials:

1-Heptyne

chlorodiisopropylsilane

(E)-diisopropyl-(1-heptenyl)silyl chloride

sodium hydrogencarbonate

Downstream raw materials:

(E)-1-heptenylbenzene