Sodium bicarbonate

Base Information

• Chemical Name: Sodium bicarbonate
• CAS No.: 144-55-8
• Molecular Formula: NaHCO3
• Molecular Weight: 84.0069
• Hs Code.: 28363000
• Mol file: 144-55-8.mol

Synonyms:Carbonic acid, monosodium salt;Natriumhydrogenkarbonat;Meylon;Carbonic acid disodium salt;SodaSee;Monosodium hydrogen carbonate;Monosodium carbonate;monosodium salt ;; see the subdivided heading;Component of Col-Evac;Soda Mint;Sodium bicarbonate(1:1);Carbonic acid, disodium salt;Natriumbicarbonat, Natriumhydrogencarbonat;Sodium Bicarbonate food grade;

Chemical Property of Sodium bicarbonate

Chemical Property:

• Appearance/Colour: white powder or crystals
• Vapor Pressure: 2.58E-05mmHg at 25°C
• Melting Point: 50 °C, 323 K, 122 °F (decomposes)
• Refractive Index: 1.500
• Boiling Point: 333.6 °C at 760 mmHg
• PKA: (1) 6.37, (2) 10.25 (carbonic (at 25℃)
• Flash Point: 169.8 °C
• PSA: 60.36000
• Density: 2.173 g/cm³
• LogP: -1.11230
• Storage Temp.: 2-8°C
• Solubility.: H2O: 1 M at 20 °C, clear, colorless
• Water Solubility.: 9 g/100 mL (20 ºC)

Purity/Quality:

99.5% ^*data from raw suppliers

Sodium hydrogen carbonate, ACS, 99.7-100.3% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Description: Sodium bicarbonate, which is the compound commonly called baking soda, exists as a white, odorless, crystalline solid. It occurs naturally as the mineral nahcolite, which derives its name from its chemical formula by replacing the “3” in NaHCO3 with the ending “lite.” The world’s main source of nahcolite is the Piceance Creek Basin in western Colorado, which is part of the larger Green River formation. Sodium bicarbonate is extracted using solution mining by pumping hot water through injection wells to dissolve the nahcolite from the Eocene beds where it occurs 1,500 to 2,000 feet below the surface. The dissolved sodium bicarbonate is pumped to the surface where it is treated to recover NaHCO3 from solution. Sodium bicarbonate can also be produced from the trona deposits, which is a source of sodium carbonates (see Sodium Carbonate).
• Physical properties: White crystalline powder or granules; monoclinic crystals; density 2.20 g/cm3; decomposes around 50°C, begins to lose carbon dioxide; converts to sodium carbonate at 100°C; soluble in water, 10g/100 mL at 20°C; slowly decomposes to CO2 and Na2CO3 in aqueous solution at ambient temperature; decomposes to Na2CO3 in boiling water; aqueous solution slightly alkaline; pH of 0.1M solution at 25°C is about 8.3; insoluble in alcohol; decomposes in acids.
• Uses: Sodium bicarbonate, used in the formof baking soda and baking powder, is the most common leavening agent. When baking soda,which is an alkaline substance, is added to a mix, it reacts with an acid ingredient to producecarbon dioxide. The reaction can be represented as: NaHCO3(s) + H+ → Na+(aq) + H2O(l) +CO2(g), where H+ is supplied by the acid. Baking powders contain baking soda as a primaryingredient along with acid and other ingredients. Depending on the formulation, bakingpowders can produce carbon dioxide quickly as a single action powder or in stages, as with adouble-action powder. Baking soda is also used as a source of carbon dioxide for carbonatedbeverages and as a buffer.In addition to baking, baking soda has numerous household uses. It is used as a generalcleanser, a deodorizer, an antacid, a fire suppressant, and in personal products such as toothpaste.Sodium bicarbonate is a weak base in aqueous solution, with a pH of about 8. Thebicarbonate ion (HCO3-) has amphoteric properties, which means it can act as either an acidor a base. This gives baking soda a buff ering capacity and the ability to neutralize both acidsand bases. Food odors resulting from acidic or basic compounds can be neutralized with bakingsoda into odor-free salts. Because sodium bicarbonate is a weak base, it has a greater abilityto neutralize acid odors.The second largest use of sodium bicarbonate, accounting for approximately 25% of totalproduction, is as an agricultural feed supplement. In cattle it helps maintain rumen pH andaids fiber digestibility; for poultry it helps maintain electrolyte balance by providing sodiumin the diet, helps fowl tolerate heat, and improves eggshell quality.Sodium bicarbonate is used in the chemical industry as a buff ering agent, a blowingagent, a catalyst, and a chemical feedstock. Sodium bicarbonate is used in the leather tanningindustry for pretreating and cleaning hides and to control pH during the tanning process.Heating sodium bicarbonate produces sodium carbonate, which is used for soap and glassmaking.Sodium bicarbonate is incorporated into pharmaceuticals to serve as an antacid, abuff ering agent, and in formulations as a source of carbon dioxide in eff ervescent tablets. Drychemical type BC fire extinguishers contain sodium bicarbonate (or potassium bicarbonate).Other uses of bicarbonate include pulp and paper processing, water treatment, and oil welldrilling. Sodium Bicarbonate is a leavening agent with a ph of approxi- mately 8.5 in a 1% solution at 25°c. it functions with food grade phosphates (acidic leavening compounds) to release carbon dioxide which expands during the baking process to provide the baked good with increased volume and tender eating qualities. it is also used in dry-mix beverages to obtain carbonation, which results when water is added to the mix containing the sodium bicarbonate and an acid. it is a component of baking powder. it is also termed baking soda, bicarbonate of soda, sodium acid carbonate, and sodium hydrogen carbonate. manufacture of many sodium salts; source of CO2; ingredient of baking powder, effervescent salts and beverages; in fire extinguishers, cleaning Compounds. sodium bicarbonate (baking soda) is an inorganic salt used as a buffering agent and a pH adjuster, it also serves as a neutralizer. It is used in skin-smoothing powders.
• Clinical Use: Metabolic acidosis Alkalinisation of urine Renoprotection against contrast media
• Drug interactions: Potentially hazardous interactions with other drugs Increases lithium excretion.

Technology Process of Sodium bicarbonate

There total 170 articles about Sodium bicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98%

CYANAMID (420-04-2) + sodium hydroxide (1310-73-2) → sodium cyanamide (19981-17-0,20611-81-8,123092-13-7,17292-62-5) + sodium hydrogencarbonate (144-55-8)

Guidance literature:

In methanol; after N. A. Gol'dberg and V. G. Golov, Zh. Prikl. Khim., 35, 2106 (1962);

Reference yield: 30%

Na(1+)*H(1+)*W2(CO)10(2-)=NaHW2(CO)10 → triphenylphosphine tungsten pentacarbonyl (15444-65-2) + trans-triphenylphosphane tetracarbonyltungsten (16743-03-6,38800-77-0,68738-00-1) + sodium formate (141-53-7) + sodium hydrogencarbonate (144-55-8) + sodium carbonate (497-19-8)

Guidance literature:

With carbon dioxide; triphenylphosphine; In acetonitrile; Irradiation (UV/VIS); (Ar or N2); UV irradn. (>420 nm) of soln. of W compd. and PPh3 with stirring at ca. 20°C for ca. 12 h under CO2 pressure, formed ppt. was sepd.; W compds. were detected IR spect. in filtrate, not isolated; NaHCOO detected 1HNMR spect. in D2O soln. of ppt.; Na2CO3 and NaHCO3 detd. in aq. soln. of ppt. by titrn.;

Reference yield:

Sodium borate + carbonic-acid (463-79-6) → metaboric acid (13460-50-9) + sodium hydrogencarbonate (144-55-8)

Guidance literature:

In water; equilibrium reaction;;

upstream raw materials:

1,3,5-trichloro-2,4,6-triazine

(1-carbamoylmethyl-cyclohexylmethyl)-carbamic acid tert-butyl ester

5-[N-tert-butoxycarbonyl-N-[5-(trifluoromethanesulfonamido)pentan-1-yl]aminomethyl]-imidazo[1,2-a]pyridine

trifluoroacetyl chloride

Downstream raw materials:

4,6-bis-dimethylamino-[1,3,5]oxadiazin-2-one

carboxybiotin

(R)-(+)-4-vinyl-1,3-dioxolan-2-one

(S)-4-vinyl-1,3-dioxolan-2-one

Refernces

• 1、 Oglesby, N. E.. "-". . p. 2352 - 2362. Retrieved 1929.
• 2、 Liebing, Phil,Schmeide, Marten,Kühling, Marcel,Witzorke, Juliane. "The Alkali Metal Salts of Methyl Xanthic Acid". . p. 2428 - 2434. Retrieved 2020.
• 3、 Wegscheidep, R.,Mehl, J.. "". . . Retrieved 1928.
• 4、 Galven, Cyrille,Pagnier, Thierry,Rosman, No?l,Le Berre, Fran?oise,Crosnier-Lopez, Marie-Pierre. "β-Na2TeO4: Phase Transition from an Orthorhombic to a Monoclinic Form. Reversible CO2 Capture". . p. 7334 - 7345. Retrieved 2018.
• 5、 Barrett, Seth M.,Slattery, Samuel A.,Miller, Alexander J. M.. "Photochemical Formic Acid Dehydrogenation by Iridium Complexes: Understanding Mechanism and Overcoming Deactivation". . p. 6320 - 6327. Retrieved 2015.
• 6、 -. "CATALYTIC CONVERSION OF CARBON DIOXIDE TO METHANOL". Page/Page column 25; 26. . Retrieved 2019/10/29.