Technology Process of C27H43IO4Si
There total 13 articles about C27H43IO4Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C17H36OSi2;
With
tin(IV) chloride;
In
dichloromethane;
at -78 ℃;
for 0.75h;
C13H15IO3;
In
dichloromethane;
at -78 ℃;
for 3h;
With
water; sodium hydrogencarbonate; triethylamine;
In
dichloromethane;
at -78 - 20 ℃;
DOI:10.1016/j.tet.2011.07.066
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 0.5 h / 0 °C
2.1: potassium carbonate / methanol / 1.17 h / 0 - 20 °C
3.1: tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride / tetrahydrofuran / 0.33 h
4.1: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C
5.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1.5 h
6.1: tin(IV) chloride / dichloromethane / 0.75 h / -78 °C
6.2: 3 h / -78 °C
6.3: -78 - 20 °C
With
tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride; sulfur trioxide pyridine complex; tin(IV) chloride; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; dichloromethane; toluene;
6.1: Sakurai reaction / 6.2: Sakurai reaction;
DOI:10.1016/j.tet.2011.07.066
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C
2.1: tin(IV) chloride / dichloromethane / 0.75 h / -78 °C
2.2: 3 h / -78 °C
2.3: -78 - 20 °C
With
2,6-dimethylpyridine; tin(IV) chloride;
In
dichloromethane;
2.1: Sakurai reaction / 2.2: Sakurai reaction;
DOI:10.1016/j.tet.2011.07.066
