tri-Boc-hydrazinoacetic acid

Base Information

Chemical Name:tri-Boc-hydrazinoacetic acid
CAS No.:261380-41-0
Molecular Formula:C17H30 N2 O8
Molecular Weight:390.434
Hs Code.:
European Community (EC) Number:626-976-3
Nikkaji Number:J1.229.904D
Mol file:261380-41-0.mol

Synonyms:tri-Boc-hydrazinoacetic acid;261380-41-0;2-(1,2,2-Tris(tert-butoxycarbonyl)hydrazinyl)acetic acid;2-[[bis[(2-methylpropan-2-yl)oxycarbonyl]amino]-[(2-methylpropan-2-yl)oxycarbonyl]amino]acetic acid;(Boc)2NN(Boc)CH2CO2H;SCHEMBL290255;Tri-tert-butyl N-(carboxymethyl)hydrazinetricarboxylate;FSRNHDLQBNOYJK-UHFFFAOYSA-N;MFCD06201012;AKOS015894034;SB86353;1,1,2-Hydrazinetricarboxylic acid, 2-(carboxymethyl)-, 1,1,2-tris(1,1-dimethylethyl) ester;AS-74393;CS-0336139;Tri-Boc-hydrazinoacetic acid, >=97.0% (N);[Tris(tert-butyloxycarbonyl)hydrazino]acetic acid;J-016275;2-(1,2,2-Tris(tert-butoxycarbonyl)hydrazinyl)aceticacid;N-(bis(tert-butoxycarbonyl)amino)-N-(tert-butoxycarbonyl)glycine;2-({bis[(tert-butoxy)carbonyl]amino}[(tert-butoxy)carbonyl]amino)acetic acid

Suppliers and Price of tri-Boc-hydrazinoacetic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Tri-Boc-hydrazinoacetic acid ≥97.0%(N)
1 g
$ 195.00

Sigma-Aldrich
Tri-Boc-hydrazinoacetic acid ≥97.0% (N)
1g-f
$ 185.00

Crysdot
2-(1,2,2-Tris(tert-butoxycarbonyl)hydrazinyl)aceticacid 95+%
5g
$ 621.00

American Custom Chemicals Corporation
TRI-BOC-HYDRAZINOACETIC ACID 95.00%
0.1MG
$ 1123.82

AK Scientific
Tri-Boc-hydrazinoacetic acid
250mg
$ 151.00

Total 8 raw suppliers

Chemical Property of tri-Boc-hydrazinoacetic acid

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:112-115 °C
Refractive Index:1.49
Boiling Point:451.672°C at 760 mmHg
Flash Point:226.963°C
PSA：143.25000
Density:1.187g/cm³
LogP:2.44140
Storage Temp.:2-8°C
XLogP3:3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:8
Exact Mass:390.20021592
Heavy Atom Count:27
Complexity:553

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tri-Boc-hydrazinoacetic acid ≥97.0%(N) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC(C)(C)OC(=O)N(CC(=O)O)N(C(=O)OC(C)(C)C)C(=O)OC(C)(C)C

Technology Process of tri-Boc-hydrazinoacetic acid

There total 6 articles about tri-Boc-hydrazinoacetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 609366-54-3
benzyl [N,N,N'-tris(tert-butyloxycarbonyl)hydrazino]acetate

: 261380-41-0
[N,N,N'-tris(tert-butyloxycarbonyl)hydrazino]acetic acid

Guidance literature:: With hydrogen; palladium dihydroxide; In ethanol; at 4 ℃; for 24h; atmospheric pressure;
DOI:10.1021/jo0343432

Reference yield:

: 870-46-2
t-butoxycarbonylhydrazine

: 261380-41-0
[N,N,N'-tris(tert-butyloxycarbonyl)hydrazino]acetic acid

Guidance literature:: Multi-step reaction with 3 steps

1: dimethylformamide / 8 h / 20 °C

2: Et₃N; DMAP / CH₂Cl₂ / 0 - 20 °C

3: 9.6 g / aq. NaOH / ethanol / 0.42 h / 0 °C

With dmap; sodium hydroxide; triethylamine; In ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo0343432

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 261380-41-0
[N,N,N'-tris(tert-butyloxycarbonyl)hydrazino]acetic acid

Guidance literature:: Multi-step reaction with 3 steps

1: N-methylmorpholine / H₂O; ethanol / 2.25 h / 0 - 20 °C

2: Et₃N; DMAP / CH₂Cl₂ / 0 - 20 °C

3: 9.6 g / aq. NaOH / ethanol / 0.42 h / 0 °C

With 4-methyl-morpholine; dmap; sodium hydroxide; triethylamine; In ethanol; dichloromethane; water;
DOI:10.1021/jo0343432