1H-Indole,7-methyl-,radicalion(1+)(9CI)

Base Information

• Chemical Name: 1H-Indole,7-methyl-,radicalion(1+)(9CI)
• CAS No.: 261352-51-6
• Molecular Formula: C₉H₉N
• Molecular Weight: 131.177
• Mol file: 261352-51-6.mol

Synonyms:1H-Indole,7-methyl-,radicalion(1+)(9CI)

Chemical Property of 1H-Indole,7-methyl-,radicalion(1+)(9CI)

Chemical Property:

Purity/Quality:

7-METHYL-1H-INDOLE RADICALION(1+) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1H-Indole,7-methyl-,radicalion(1+)(9CI)

There total 67 articles about 1H-Indole,7-methyl-,radicalion(1+)(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,3-dihydro-7-methylindole (65673-86-1) → 7-methyl-1H-indole (933-67-5,261352-51-6)

Guidance literature:

With 6C₄₄H₃₂N₆O₄Ru⁽²⁺⁾*12Hf⁽²⁺⁾*8O^(2-)*14HO^(1-)*6C₁₆H₂₂ClCoN₅O₆^(1-); In 2,2,2-trifluoroethanol; acetonitrile; at 20 ℃; for 12h; Reagent/catalyst; Catalytic behavior; Inert atmosphere; Irradiation;

DOI:10.1002/anie.202011519

Reference yield: 93.0%

7-methyl-1-pivaloylindole → 7-methyl-1H-indole (933-67-5,261352-51-6)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; hexane; at 40 - 45 ℃; for 40h;

DOI:10.1055/s-2004-836060

Reference yield: 84.0%

7-methyl-1-tosylindoline → 7-methyl-1H-indole (933-67-5,261352-51-6)

Guidance literature:

7-methyl-1-tosylindoline; In tetrahydrofuran; at -78 ℃; for 2h;

With oxygen; In tetrahydrofuran; at 20 ℃;

DOI:10.1002/chem.201705202

upstream raw materials:

7-methyl-1H-indole-2,3-dione

1-methyl-2-nitrobenzene

vinyl magnesium bromide

1-(2-amino-3-methylphenyl)-2-chloroethan-1-one

Downstream raw materials:

1,4,8-trimethyl-carbazole

7-methyl-1H-indole-3-carboxylic acid

7-methylindole radical

1,7-dimethyl-1H-indole

Refernces

• 1、 Quan, Yangjian,Lan, Guangxu,Shi, Wenjie,Xu, Ziwan,Fan, Yingjie,You, Eric,Jiang, Xiaomin,Wang, Cheng,Lin, Wenbin. "Metal–Organic Layers Hierarchically Integrate Three Synergistic Active Sites for Tandem Catalysis". supporting information. p. 3115 - 3120. Retrieved 2020/12/09.
• 2、 Cao, Yue,Wu, Yong,Zhang, Yuanteng,Zhou, Jing,Xiao, Wei,Gu, Dong. "Highly Ordered Mesoporous Cobalt Oxide as Heterogeneous Catalyst for Aerobic Oxidative Aromatization of N-Heterocycles". . p. 3679 - 3686. Retrieved 2021/06/18.