Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2

Base Information

• Chemical Name: Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2
• CAS No.: 87101-18-6
• Molecular Formula: C₅₈H₅₁I₂NP₄Pt₂
• Molecular Weight: 1529.91
• Mol file: 87101-18-6.mol

Synonyms:Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2

Chemical Property of Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2

There total 1 articles about Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

{Pt2I2(μ-1,2-bis(diphenylphosphino)methane)2} (61289-07-4) + 4-methylphenyl isocyanide (7175-47-5) → Pt2I2(CH3C6H4NC)((C6H5)2PCH2P(C6H5)2)2 (87101-18-6)

Guidance literature:

In diethyl ether; dichloromethane; under N2, to a soln. of the Pt-complex in CH2Cl2 is added a soln. of 1 equiv of CH3C6H4CN, Et2O added until pptn. commenced; filtered, recrystd. from CH2Cl2-Et2O, vac. dried at 100°C; elem. anal.;

DOI:10.1021/om50006a006

Reference yield: 95.0%

Pt2I2(CH3C6H4NC)((C6H5)2PCH2P(C6H5)2)2 (87101-18-6) → Pt2I2(CH3C6H4N(CH3)C)((C6H5)2PCH2P(C6H5)2)2(1+)*I(1-)=(Pt2I2(CN(CH3)C6H4CH3)((C6H5)2PCH2P(C6H5)2)2)I (87114-15-6)

Guidance literature:

With CH₃I; In dichloromethane; under N2, to a suspn. of Pt2I2(CNC6H4CH3)(dppm)2 in CH2Cl2 is added CH3I, mixt. stirred, product pptd. by the addition of Et2O; filtered, recrystd. from CH2Cl2-EtOH, vac. dried at 100°C; elem. anal.;

DOI:10.1021/om50006a006

Reference yield: 80.0%

Pt2I2(CH3C6H4NC)((C6H5)2PCH2P(C6H5)2)2 (87101-18-6) → Pt2I2(CH3C6H4N(H)C)((C6H5)2PCH2P(C6H5)2)2(1+)*ClO4(1-)=(Pt2I2(CN(H)C6H4CH3)((C6H5)2PCH2P(C6H5)2)2)ClO4 (87101-19-7)

Guidance literature:

With HClO₄; In ethanol; dichloromethane; under N2, to a suspn. of Pt2I2(CNC6H4CH3)(dppm)2 in CH2Cl2 is added ethanol and 70% HClO4, stirred; evapd. under reduced pressure, filtered, washed with acidified (70% HClO4) EtOH and hexane, recrystd. from CH2Cl2-acidified EtOH, vac. dried at 100°C; elem. anal.;

DOI:10.1021/om50006a006

upstream raw materials:

{Pt2I2(μ-1,2-bis(diphenylphosphino)methane)2}

4-methylphenyl isocyanide

Downstream raw materials:

Pt₂I₂(CH₃C₆H₄N(CH₃)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*I^(1-)=(Pt₂I₂(CN(CH₃)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)I

Pt₂I₂(CH₃C₆H₄N(H)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*ClO₄^(1-)=(Pt₂I₂(CN(H)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)ClO₄