61289-07-4

Upstream product

• 75-30-9 2-iodo-propane 
• 2314-97-8 iodotrifluoromethane 
• 558-17-8 tert-Butyl iodide 
• 591-50-4 iodobenzene 
• 556-56-9 allyl iodid 
• 61250-65-5 dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) 
• 7681-82-5 sodium iodide 

Downstream Products

• 87101-11-9 Pt₂I(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*PF₆^(1-)=(Pt₂I(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2)PF₆ 
• 137966-80-4 Pt₂I₂(NO)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)={Pt₂I₂(NO)((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄ 
• 102494-79-1 Pt₂I₂(S)(CH₂(P(C₆H₅)2)2)2 
• 87101-18-6 Pt₂I₂(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2 

Relevant academic research and scientific papers

Synthesis, characterization, and reactivity of a platinum(0) dimer: Pt2(μ-CO)(CO)2(μ-dppm)2

The zerovalent platinum dimer [Pt2(μ-CO)(CO)2(μ-dppm)2] (1) (dppm = Ph2PCH2PPh2) has been prepared from [Pt2Cl2(μ-dppm)2] (2) via sodium borohydride reduction under carbon monoxide and from [Pt2(μ-dppm)3] (3) by substitution of a dppm ligand with CO. This latter reaction is readily reversible and can undergo several cycles of carbonylation-decarbonylation. Complex 1 undergoes typical oxidative addition reactions; it is readily protonated to yield [Pt2(H)(CO)(μ-dppm)2]-(p-CH3C 6H4SO3)·C6H6 (4). With I2, 1 reacts to yield [Pt2I2(μ-dppm)2] (5), and reaction with CH3I produces [Pt2(μ-I)(CH3)2(μ-dppm)2]I (6).

Some Alkyldiplatinum(I) Complexes and Studies of the Photochemical and Thermal Decomposition of the + Cation

The first alkyldiplatinum(I) complexes containing β-hydrogen atoms, - (R=Et, CD3CH2, Pr, or Bu; dppm=Ph2PCH2PPh2), were prepared by reaction of with RI followed by addition of K.The complexes were yellow, air-stable solids which were characterized by 1H and 31P n.m.r. spectroscopy.Photochemical or thermal decomposition of the ethyl derivative was shown to involve β elimination, which occured subsequent to the rate-determining step.