(6-Oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester

Base Information

Chemical Name:(6-Oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester
CAS No.:939759-29-2
Molecular Formula:C₁₈H₁₇NO₃
Molecular Weight:295.338
Hs Code.:
DSSTox Substance ID:DTXSID501169066

Synonyms:939759-29-2;(6-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester;DTXSID501169066;MB06395;(6-OXO-5,6,7,8-TETRAHYDRO-NAPHTHALEN-2-YL)-CARBAMIC ACID BENZYL ESTER;Phenylmethyl N-(5,6,7,8-tetrahydro-6-oxo-2-naphthalenyl)carbamate

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Chemical Property of (6-Oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:295.12084340
Heavy Atom Count:22
Complexity:403

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC2=C(CC1=O)C=CC(=C2)NC(=O)OCC3=CC=CC=C3

Technology Process of (6-Oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester

There total 4 articles about (6-Oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 164148-65-6
1,2-dihydroxy-6-[[(phenylmethoxy)carbonyl]amino]-1,2,3,4-tetrahydronaphthylene

: 939759-29-2
(6-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: With toluene-4-sulfonic acid; In toluene; for 1h; Heating;
DOI:10.1021/jm990365y

Reference yield:

: 164148-64-5
7-[[(phenylmethoxy)carbonyl]amino]-1,2-dihydronaphthylene

: 939759-29-2
(6-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: N-methylmorpholine N-oxide; aq. OsO₄ / 2-methyl-propan-2-ol; acetone / 6 h / 20 °C

2: TsOH / toluene / 1 h / Heating

With osmium(VIII) oxide; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In acetone; toluene; tert-butyl alcohol; 1: dihydroxylation / 2: Dehydration;
DOI:10.1021/jm990365y

Reference yield:

: 164149-25-1
(5-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

: 939759-29-2
(6-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: NaBH₄ / ethanol / 5 h / 20 °C

2: TsOH / benzene / 1 h / Heating

3: N-methylmorpholine N-oxide; aq. OsO₄ / 2-methyl-propan-2-ol; acetone / 6 h / 20 °C

4: TsOH / toluene / 1 h / Heating

With sodium tetrahydroborate; osmium(VIII) oxide; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In ethanol; acetone; toluene; tert-butyl alcohol; benzene; 1: Reduction / 2: Dehydration / 3: dihydroxylation / 4: Dehydration;
DOI:10.1021/jm990365y