benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate

Base Information

Chemical Name:benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate
CAS No.:164149-25-1
Molecular Formula:C18H17NO3
Molecular Weight:295.33200
Hs Code.:2924299090
Mol file:164149-25-1.mol

Synonyms:4-IMIDAZOLIDINEACETIC ACID,1-(2-METHYLPHENYL)-5-OXO-2-THIOXO;(5-oxo-2-thioxo-1-o-tolyl-imidazolidin-4-yl)-acetic acid;(5-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester;1-(2-Methylphenyl)-5-oxo-2-thioxo-4-imidazolidineacetic acid;

Suppliers and Price of benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Benzyl(5-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamate 95+%
1g
$ 353.00

American Custom Chemicals Corporation
BENZYL-(5-OXO-5,6,7,8-TETRAHYDRONAPHTHALEN-2-YL)CARBAMATE 95.00%
5MG
$ 496.79

Alichem
Benzyl(5-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamate
1g
$ 400.00

Total 4 raw suppliers

Chemical Property of benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate

Chemical Property:

Boiling Point:443.8±44.0 °C(Predicted)
PKA:13.24±0.20(Predicted)
PSA：55.40000
Density:1.268±0.06 g/cm3(Predicted)
LogP:4.02730
Storage Temp.:2-8°C

Purity/Quality:

99% ^*data from raw suppliers

Benzyl(5-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)carbamate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate

There total 1 articles about benzyl 5-oxo-5,6,7,8-tetrahydronaphthalen-2-ylcarbaMate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 3470-53-9
6-amino-1-tetralone

: 501-53-1,94274-21-2
benzyl chloroformate

: 164149-25-1
(5-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: With sodium hydrogencarbonate; In tetrahydrofuran; at 0 - 20 ℃;

Reference yield:

: 164149-25-1
(5-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

: (5-hydroxy-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: With sodium tetrahydroborate; In ethanol; at 20 ℃; for 5h;
DOI:10.1021/jm990365y

Reference yield:

: 164149-25-1
(5-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

: 939759-29-2
(6-oxo-5,6,7,8-tetrahydro-naphthalen-2-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: NaBH₄ / ethanol / 5 h / 20 °C

2: TsOH / benzene / 1 h / Heating

3: N-methylmorpholine N-oxide; aq. OsO₄ / 2-methyl-propan-2-ol; acetone / 6 h / 20 °C

4: TsOH / toluene / 1 h / Heating

With sodium tetrahydroborate; osmium(VIII) oxide; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In ethanol; acetone; toluene; tert-butyl alcohol; benzene; 1: Reduction / 2: Dehydration / 3: dihydroxylation / 4: Dehydration;
DOI:10.1021/jm990365y