acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

Base Information

• Chemical Name: acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)
• CAS No.: 67913-10-4
• Molecular Formula: C₂₈H₂₇I₂OP₂Rh
• Molecular Weight: 798.184
• Mol file: 67913-10-4.mol

Synonyms:acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

Chemical Property of acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III)

There total 11 articles about acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[rhodium(III)diiodide(acetyl)(carbonyl)(NCMe)]2 (756480-18-9) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → [Rh(COCH3)I2(bis(1,2-diphenylphosphino)ethane)] (67913-10-4)

Guidance literature:

In dichloromethane; dppe and Rh complex were dissolved in CH2Cl2 and warmed to gentle refluxfor 1 h; Et2O was added, 24 h at -10°C, ppt. was filtered; elem. anal.;

DOI:10.1016/j.ica.2004.03.018

Reference yield: 74.0%

Rh{(C6H5)2P(CH2)2P(C6H5)2}(CO)I (122924-43-0) → acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III) (67913-10-4)

Guidance literature:

With methyl iodide; In dichloromethane; under protective gas; Rh-complex dissolved in CH2Cl2; addn. of CH3I; reaction time 9h; reaction monitored by IR and NMR spectroscopies; analysis;

DOI:10.1021/om00114a025

Reference yield: 70.0%

Rh{(C6H5)2P(CH2)2P(C6H5)2}(CO)I (122924-43-0) + methyl iodide (74-88-4) → acetyl(bis-1,2-(diphenylphosphino)ethane)diiodorhodium(III) (67913-10-4)

Guidance literature:

In dichloromethane; under N2 atm. using Schlenk techniques; Rh complex dissolved in CH2Cl2; excess MeI added; soln. stirred at room temp. for 3 h; soln. concd. (vac.); pptd. by addition of Et2O after cooling to -10°C for 24 h; elem. anal.;

DOI:10.1021/ja0176191

upstream raw materials:

Rh{(C₆H₅)2P(CH₂)2P(C₆H₅)2}(CO)I

methyl iodide

Rh(CO)I₂(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)(methyl)

1,2-bis-(diphenylphosphino)ethane