Re₂(CO)9(C⁽²⁾H₃CN)

Base Information

Chemical Name:Re₂(CO)9(C⁽²⁾H₃CN)
CAS No.:98688-84-7
Molecular Formula:C₁₁H₃NO₉Re₂
Molecular Weight:668.536
Hs Code.:

Re<sub>2</sub>(CO)9(C<sup>(2)</sup>H<sub>3</sub>CN)

Synonyms:Re₂(CO)9(C⁽²⁾H₃CN)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Re₂(CO)9(C⁽²⁾H₃CN)

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Technology Process of Re₂(CO)9(C⁽²⁾H₃CN)

There total 4 articles about Re₂(CO)9(C⁽²⁾H₃CN) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 75149-83-6
ethylpentacarbonylrhenium

: 2206-26-0
[D₃]acetonitrile

: 98688-84-7
Re₂(CO)9(C⁽²⁾H₃CN)

: 123-38-6
propionaldehyde

Guidance literature:: In [D₃]acetonitrile; under N2 flow EtRe(CO)5 in CD3CN was added via syringe to an NMR tube, the contents were frozen and degassed, and HRe(CO)5 (1:1 ratio) was added via vac. transfer, the tube was sealed and heated (60°C) for 27h; monitored by (1)H NMR, Re2(CO)9(CD3CN) was isolated by preparative layer chromy.; elem. anal., yield of EtCHO was detd. by the integration of the corresponding peak in the (1)H NMR spectrum;

Reference yield: 42.0%

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 59599-35-8
dimethyl(tetracarbonyl)osmium

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 34557-54-5,27936-85-2
methane

: 98688-84-7
Re₂(CO)9(C⁽²⁾H₃CN)

: 98688-92-7
Re₂Os*13CO*C⁽²⁾H₃CN=Re₂Os(CO)13(C⁽²⁾H₃CN)

: 75-07-0,9002-91-9
acetaldehyde

Guidance literature:: In [D₃]acetonitrile; Me2Os(CO)4, HRe(CO)5 (1:4 molar ratio), and CD3CN were sealed in an NMRtube and heated at 60°C for 10 d; the tube was broken open on the vac. line, volatile components (-196°C) were collected via a Toepler pump, and analysed by GC, nonvolatile residue was subjected to preparative layer chromy.; yield of MeCHO was detd. by (1)H NMR, of CH4 - by GC;

Reference yield:

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 98688-98-3
C₂H₅C(O)Re(CO)4(C⁽²⁾H₃CN)

: 98688-84-7
Re₂(CO)9(C⁽²⁾H₃CN)

: 123-38-6
propionaldehyde

Guidance literature:: In [D₃]acetonitrile; a tube with CD3CN soln. of acyl solvate (prepd. in situ) was attached to vac. line, frozen, evacuated, excess of HRe(CO)5 was added, the sealedtube warmed to room temp.; monitored by (1)H NMR;