4-(undec-10-enyloxy)phenyl 4-formylbenzoate

Base Information

• Chemical Name: 4-(undec-10-enyloxy)phenyl 4-formylbenzoate
• CAS No.: 1185417-86-0
• Molecular Formula: C₂₅H₃₀O₄
• Molecular Weight: 394.511
• Mol file: 1185417-86-0.mol

Synonyms:4-(undec-10-enyloxy)phenyl 4-formylbenzoate

Chemical Property of 4-(undec-10-enyloxy)phenyl 4-formylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(undec-10-enyloxy)phenyl 4-formylbenzoate

There total 1 articles about 4-(undec-10-enyloxy)phenyl 4-formylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

4-Carboxybenzaldehyde (619-66-9) + p-hydroxyphenyl undec-10-en-1-yl ether (117721-44-5) → 4-(undec-10-enyloxy)phenyl 4-formylbenzoate (1185417-86-0)

Guidance literature:

4-Carboxybenzaldehyde; p-hydroxyphenyl undec-10-en-1-yl ether; With dmap; In dichloromethane; for 0.166667h;

With dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1039/b907536d

Reference yield: 72.0%

4-(undec-10-enyloxy)phenyl 4-formylbenzoate (1185417-86-0) → 4-[4-(undec-10-enyloxy)phenoxycarbonyl]benzoic acid (1185417-88-2)

Guidance literature:

4-(undec-10-enyloxy)phenyl 4-formylbenzoate; With sodium chlorite; sodium dihydrogen phosphate monohydrate; recorcinol; In water; tert-butyl alcohol; at 20 ℃;

With hydrogenchloride; In water; pH=2;

DOI:10.1039/b907536d

Reference yield:

4-(undec-10-enyloxy)phenyl 4-formylbenzoate (1185417-86-0) → 2-methyl-1,3-phenylene bis(4-{4-[11-(1,1,3,3,5,5,5-heptamethyltrisiloxane-1-yl)undec-1-yloxy]phenoxycarbonyl}benzoate) (1185417-85-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium chlorite; sodium dihydrogen phosphate monohydrate; recorcinol / water; tert-butyl alcohol / 20 °C

1.2: pH 2

2.1: dmap / dichloromethane / 0.17 h

2.2: 12 h / 20 °C

3.1: platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex / toluene / 20 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogen phosphate monohydrate; platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; recorcinol; In dichloromethane; water; toluene; tert-butyl alcohol;

DOI:10.1039/b907536d

upstream raw materials:

4-Carboxybenzaldehyde

p-hydroxyphenyl undec-10-en-1-yl ether

Downstream raw materials:

4-[4-(undec-10-enyloxy)phenoxycarbonyl]benzoic acid

2-methyl-1,3-phenylene bis(4-{4-[11-(1,1,3,3,5,5,5-heptamethyltrisiloxane-1-yl)undec-1-yloxy]phenoxycarbonyl}benzoate)