[Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂]

Base Information

• Chemical Name: [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂]
• CAS No.: 1601494-27-2
• Molecular Formula: C₃₃H₂₉Br₂MoN₃O₂P₂
• Molecular Weight: 817.308
• Mol file: 1601494-27-2.mol

Synonyms:[Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂]

Chemical Property of [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂]

There total 3 articles about [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₂Br₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

N,N′-bis(diphenylphosphino)-N,N′-dimethyl-2,6-diaminopyridine (1601494-24-9) + [molybdenum(II)(carbonyl)4(μ-bromide)bromide]2 → [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)2Br2] (1601494-27-2)

Guidance literature:

In acetonitrile; for 18h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2013.12.018

Reference yield:

[Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)3] (1601494-25-0) + bromine (7726-95-6) → [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)2Br2] (1601494-27-2)

Guidance literature:

In acetonitrile; at -78 - 20 ℃; for 18h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2013.12.018

Reference yield:

N,N′-bis(diphenylphosphino)-N,N′-dimethyl-2,6-diaminopyridine (1601494-24-9) + C6H6Br2MoN2O2 → [Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)2Br2] (1601494-27-2)

Guidance literature:

In acetonitrile; for 18h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2013.12.018

upstream raw materials:

N,N′-bis(diphenylphosphino)-N,N′-dimethyl-2,6-diaminopyridine

[Mo(N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine)(CO)₃]

bromine