Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

Base Information

Chemical Name:Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide
CAS No.:116911-78-5
Molecular Formula:C₁₉H₁₈N₂O₅S₂
Molecular Weight:418.494
Hs Code.:

Synonyms:Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

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Chemical Property of Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

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Technology Process of Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

There total 12 articles about Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 116911-70-7
1-(phenylsulfonyl)-4-diazo-3-methyl-5--4,7-dihydroindol-7-one

: 116911-76-3
5-Allylamino-1-benzenesulfonyl-3-methyl-1H-indole-4,7-dione

: 116911-78-5
Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

: 116911-77-4
C₁₉H₁₈N₂O₅S₂

Guidance literature:: With copper(II) sulfate; sodium nitrite; In dichloromethane; for 0.5h; Irradiation;
DOI:10.1021/jo00256a036

Reference yield:

: 25945-95-3
N-<2-(benzyloxy)-4-nitrophenyl>acetamide

: 116911-78-5
Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

Guidance literature:: Multi-step reaction with 11 steps

1: Zn, CaCl₂, ethanol / 1.5 h / Heating

2: 80 percent / pyridine / CH₂Cl₂ / 2 h / 25 °C

3: 80 percent / potessium tert-butoxide / dimethylformamide / 3 h / Ambient temperature

4: 82 percent / 50percent aq. KOH / ethanol / 8 h / Heating

5: 1.) NaNO₂, HCl, SnCl₂ / 1.) 2 h, 2.) RT, 12 h

6: 1.) NaH / 1.) THF, 0 deg C, 1 h, 2.)THF, RT, 8 h

7: ammonium nitrate, trifluoroacetic anhydride / CHCl₃ / 6 h

8: BBr₃, cyclohexane / CH₂Cl₂ / 0.5 h / -20 °C

9: 78 percent / pyridine / CH₂Cl₂ / 1 h / Ambient temperature

10: 1.) CaCl₂, Zn, aq. C₂H₅OH, 2.) isoamyl nitrite / 1.) 1 h, reflux, 2.) 0 deg C, 15 min, RT, 1h

11: 10 percent / CuSO₄, NaNO₂ / CH₂Cl₂ / 0.5 h / Irradiation

With pyridine; hydrogenchloride; potassium hydroxide; ammonium nitrate; ethanol; cyclohexane; potassium tert-butylate; boron tribromide; sodium hydride; copper(II) sulfate; trifluoroacetic anhydride; calcium chloride; tin(ll) chloride; zinc; sodium nitrite; isopentyl nitrite; In ethanol; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/jo00256a036

Reference yield:

: 25351-89-7
N-(2-hydroxy-4-nitrophenyl)acetamide

: 116911-78-5
Methanesulfinic acid allyl-(1-benzenesulfonyl-3-methyl-4,7-dioxo-4,7-dihydro-1H-indol-5-yl)-amide

Guidance literature:: Multi-step reaction with 12 steps

1: 84 percent / KI, K₂CO₃ / dimethylformamide / 4 h

2: Zn, CaCl₂, ethanol / 1.5 h / Heating

3: 80 percent / pyridine / CH₂Cl₂ / 2 h / 25 °C

4: 80 percent / potessium tert-butoxide / dimethylformamide / 3 h / Ambient temperature

5: 82 percent / 50percent aq. KOH / ethanol / 8 h / Heating

6: 1.) NaNO₂, HCl, SnCl₂ / 1.) 2 h, 2.) RT, 12 h

7: 1.) NaH / 1.) THF, 0 deg C, 1 h, 2.)THF, RT, 8 h

8: ammonium nitrate, trifluoroacetic anhydride / CHCl₃ / 6 h

9: BBr₃, cyclohexane / CH₂Cl₂ / 0.5 h / -20 °C

10: 78 percent / pyridine / CH₂Cl₂ / 1 h / Ambient temperature

11: 1.) CaCl₂, Zn, aq. C₂H₅OH, 2.) isoamyl nitrite / 1.) 1 h, reflux, 2.) 0 deg C, 15 min, RT, 1h

12: 10 percent / CuSO₄, NaNO₂ / CH₂Cl₂ / 0.5 h / Irradiation

With pyridine; hydrogenchloride; potassium hydroxide; ammonium nitrate; ethanol; cyclohexane; potassium tert-butylate; boron tribromide; sodium hydride; potassium carbonate; copper(II) sulfate; trifluoroacetic anhydride; potassium iodide; calcium chloride; tin(ll) chloride; zinc; sodium nitrite; isopentyl nitrite; In ethanol; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/jo00256a036