12Z-Tetradecenyl acetate

Base Information

• Chemical Name: 12Z-Tetradecenyl acetate
• CAS No.: 35153-20-9
• Molecular Formula: C₁₆H₃₀O₂
• Molecular Weight: 254.413
• Nikkaji Number: J684J
• Metabolomics Workbench ID: 3955
• Mol file: 35153-20-9.mol

Synonyms:12-tetradecen-1-ol acetate;12-tetradecen-1-ol acetate, (E)-isomer;12-tetradecen-1-ol acetate, (Z)-isomer;cis-12-tetradecenyl acetate;trans-12-tetradecenyl acetate

Chemical Property of 12Z-Tetradecenyl acetate

Chemical Property:

• PSA: 26.30000
• LogP: 5.02660
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 254.224580195
• Heavy Atom Count: 18
• Complexity: 209

Purity/Quality:

98%,99%, ^*data from raw suppliers

CIS-12-TETRADECENYL ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCCCCCCCCCCCOC(=O)C
• Isomeric SMILES: C/C=C\CCCCCCCCCCCOC(=O)C

Technology Process of 12Z-Tetradecenyl acetate

There total 38 articles about 12Z-Tetradecenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.1%

acetic anhydride (108-24-7) + (Z)-12-tetradecen-1-ol (70711-48-7) → (Z)-Δ12-tetradecenyl acetate (35153-20-9,35153-21-0,54897-70-0)

Guidance literature:

With pyridine; at 20 ℃; for 20h;

Reference yield: 76.0%

(Z)-Δ13-tetradecenyl acetate (56221-91-1) → (Z)-Δ12-tetradecenyl acetate (35153-20-9,35153-21-0,54897-70-0) + (E)-12-tetradecene-1-ol acetate (35153-20-9,35153-21-0,54897-70-0)

Guidance literature:

With sodium tetrahydroborate; triphenylphosphine; cobalt(II) chloride; In tetrahydrofuran; at -10 ℃; for 4h; Inert atmosphere;

DOI:10.1155/2018/1520939

Reference yield: 76.0%

(Z)-Δ13-tetradecenyl acetate (56221-91-1) → (Z)-Δ12-tetradecenyl acetate (35153-20-9,35153-21-0,54897-70-0) + (E)-12-tetradecene-1-ol acetate (35153-20-9,35153-21-0,54897-70-0)

Guidance literature:

With sodium tetrahydroborate; triphenylphosphine; cobalt(II) chloride; In tetrahydrofuran; at -10 ℃; for 4h; Inert atmosphere;

DOI:10.1155/2018/1520939

upstream raw materials:

Δ¹²-tetradecenol

acetic anhydride

Acetic acid (E)-13-trimethylsilanyl-tridec-12-enyl ester

1,8-Octanediol

Downstream raw materials:

(E)-12-tetradecene-1-ol acetate