C₅₁H₆₈O₁₁

Base Information

Chemical Name:C₅₁H₆₈O₁₁
CAS No.:457064-20-9
Molecular Formula:C₅₁H₆₈O₁₁
Molecular Weight:857.094
Hs Code.:

C<sub>51</sub>H<sub>68</sub>O<sub>11</sub>

Synonyms:C₅₁H₆₈O₁₁

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Chemical Property of C₅₁H₆₈O₁₁

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Technology Process of C₅₁H₆₈O₁₁

There total 34 articles about C₅₁H₆₈O₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 75-24-1
trimethylaluminum

: 457064-18-5
C₅₂H₇₀O₁₃S

: C₅₁H₆₈O₁₁

: 457064-20-9
C₅₁H₆₈O₁₁

Guidance literature:: In dichloromethane; at -78 - -40 ℃;
DOI:10.1021/ol026306n

Reference yield: 58.0%

: 77-76-9
2,2-dimethoxy-propane

: C₄₅H₆₀O₁₁

: C₅₁H₆₈O₁₁

: 457064-20-9
C₅₁H₆₈O₁₁

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 0.333333h;
DOI:10.1021/ol026306n

Reference yield:

: 457064-30-1
(Z)-6-((2R,4aR,6S,7R,9R,9aS)-9-Benzyloxy-7-hydroxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-hex-4-enoic acid

: 457064-20-9
C₅₁H₆₈O₁₁

Guidance literature:: Multi-step reaction with 31 steps

1.1: 2,4,6-Cl₃C₆H₂COCl; Et₃N / tetrahydrofuran / 20 °C

1.2: 71 percent / DMAP / benzene / 80 °C

2.1: 6.39 g / potassium hexamethyldisilazide; hexamethylphosphoric triamide / tetrahydrofuran; toluene / 0.67 h / -78 °C

3.1: 76 percent / triethylamine / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / dimethylformamide / 15 h / 50 °C

4.1: AD mix-α; methanesulfonamide / 2-methyl-propan-2-ol; tetrahydrofuran; H2O / 48 h / 20 °C

5.1: 79 percent / 10-camphorsulfonic acid / CH₂Cl₂ / 1 h / 20 °C

6.1: DIBALH / CH₂Cl₂; toluene / 0.5 h / -78 °C

7.1: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

8.1: dimethyldioxirane / CH₂Cl₂; acetone / 1 h / -20 °C

9.1: 75 percent / triethylsilane; BH₃*THF / CH₂Cl₂; tetrahydrofuran / 0.33 h / 0 °C

10.1: 97 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.25 h / 20 °C

11.1: 98 percent / potassium tert-butoxide / tetrahydrofuran / 0.42 h / 20 °C

12.1: ethanethiol; zinc triflate / CH₂Cl₂ / 26 h / 20 °C

13.1: 78 percent / CH₂Cl₂ / 0.33 h / 20 °C

14.1: 86 percent / ethanethiol; zinc triflate / CH₂Cl₂ / 1.83 h / 20 °C

15.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

16.1: 96 percent / camphorsulfonic acid / methanol; CH₂Cl₂ / 0.75 h / 0 °C

17.1: iodine; triphenylphosphine; imidazole / tetrahydrofuran / 1 h / 20 °C

18.1: 86 percent / potassium tert-butoxide / tetrahydrofuran / 17 h / 0 °C

19.1: tetrahydrofuran / 2 h / 20 °C

20.1: 88 percent / sodium hydrogen carbonate / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / dimethylformamide; H₂O / 17 h / 20 °C

21.1: dimethyldioxirane / CH₂Cl₂ / 0.33 h / -20 °C

22.1: 82 percent / triethylsilane; BH₃*THF / CH₂Cl₂; tetrahydrofuran / 0.25 h / -20 °C

23.1: 79.6 mg / camphorsulfonic acid / CH₂Cl₂ / 0.17 h / 20 °C

24.1: 94 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 1 h / 20 °C

25.1: 96 percent / 4-methylmorpholine N-oxide / tetrapropylammonium perruthenate / CH₂Cl₂ / 0.67 h / 20 °C

26.1: zinc triflate / CH₂Cl₂ / 18 h / 20 °C

27.1: pyridine / 18 h / 20 °C

28.1: 84 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 0.33 h / 20 °C

29.1: various solvent(s) / 0.17 h / 0 °C

30.1: potassium carbonate / methanol / 0.33 h / 60 °C

31.1: 58 percent / camphorsulfonic acid / CH₂Cl₂ / 0.33 h / 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; triethylsilane; N,N,N,N,N,N-hexamethylphosphoric triamide; AD-mix-α; borane-THF; methanesulfonamide; 2,4,6-trichlorobenzoyl chloride; camphor-10-sulfonic acid; (1S)-10-camphorsulfonic acid; potassium tert-butylate; tetrabutyl ammonium fluoride; iodine; 3,3-dimethyldioxirane; potassium hexamethylsilazane; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; ethanethiol; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrapropylammonium perruthennate; camphor-10-sulfonic acid; In tetrahydrofuran; pyridine; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 20.1: Suzuki-Miyaura coupling;
DOI:10.1021/ol026306n