p-ethylbenzyl acetate

Base Information

• Chemical Name: p-ethylbenzyl acetate
• CAS No.: 67035-84-1
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.231
• Mol file: 67035-84-1.mol

Synonyms:p-ethylbenzyl acetate

Chemical Property of p-ethylbenzyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of p-ethylbenzyl acetate

There total 8 articles about p-ethylbenzyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-ethylbenzyl alcohol (768-59-2) + acetic anhydride (108-24-7) → p-ethylbenzyl acetate (67035-84-1)

Guidance literature:

In pyridine;

Reference yield: 74.0%

4-ethylbenzyl alcohol (768-59-2) + acetyl chloride (75-36-5) → p-ethylbenzyl acetate (67035-84-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 2h;

DOI:10.1002/anie.202110233

Reference yield:

4-methylethylbenzene (622-96-8) → 1-ethenyl-4-methylbenzene (622-97-9,24936-41-2) + p-ethylbenzyl acetate (67035-84-1) + para-methylacetophenone (122-00-9) + 4-ethylbenzylaldehyde (4748-78-1)

Guidance literature:

With ammonium peroxydisulfate; copper diacetate; In water; acetic acid; at 100 ℃; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1021/jo00173a026

upstream raw materials:

sodium acetate

4-ethylbenzylchloride

4-methylethylbenzene

4-ethylbenzyl alcohol

Downstream raw materials:

4’-(acetoxymethyl)acetophenone

4-acetoxymethyl-(1-(R,S)-acetoxyethyl)benzene

4-(1-hydroxyethyl)benzyl alcohol

Refernces

• 1、 Baciocchi, Enrico,Mattioli, Mario,Romano, Roberta,Ruzziconi, Renzo. "Anodic Oxidation of α-Substituted p-Xylenes. Electronic and Stereoelectronic Effects of α-Substituents in the Deprotonation of Alkylaromatic Radical Cations". . p. 7154 - 7160. Retrieved 2007/10/02.
• 2、 Fischer, Alfred,Henderson, George N.. "ipso Nitration. XXIII. Reactions of cyclohexadiene adducts from nitration of 4-ethyltoluene in acetic anhydride". . p. 2314 - 2327. Retrieved 2007/10/02.