Technology Process of tetra(2,4,6-trideutero-phenyl)phosphonium bromide
There total 4 articles about tetra(2,4,6-trideutero-phenyl)phosphonium bromide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
nickel dichloride;
In
benzonitrile;
at 190 ℃;
for 24h;
Inert atmosphere;
DOI:10.1021/je901031b
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: hydrogen bromide; copper(I) bromide; sodium nitrite / water / 0 °C / Reflux
2.1: iodine; magnesium / diethyl ether / 1 h / Inert atmosphere; Reflux
2.2: 0.5 h / -10 - 20 °C / Inert atmosphere
3.1: nickel dichloride / benzonitrile / 24 h / 190 °C / Inert atmosphere
With
hydrogen bromide; iodine; magnesium; copper(I) bromide; nickel dichloride; sodium nitrite;
In
diethyl ether; water; benzonitrile;
DOI:10.1021/je901031b
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: water-d2 / 24 h / Reflux; Inert atmosphere
2.1: hydrogen bromide; copper(I) bromide; sodium nitrite / water / 0 °C / Reflux
3.1: iodine; magnesium / diethyl ether / 1 h / Inert atmosphere; Reflux
3.2: 0.5 h / -10 - 20 °C / Inert atmosphere
4.1: nickel dichloride / benzonitrile / 24 h / 190 °C / Inert atmosphere
With
hydrogen bromide; iodine; water-d2; magnesium; copper(I) bromide; nickel dichloride; sodium nitrite;
In
diethyl ether; water; benzonitrile;
DOI:10.1021/je901031b
