3-biphenyl-1,2-dicarba-closo-dodecaborane

Base Information

• Chemical Name: 3-biphenyl-1,2-dicarba-closo-dodecaborane
• CAS No.: 392250-97-4
• Molecular Formula: C₁₄H₂₀B₁₀
• Molecular Weight: 296.423
• Mol file: 392250-97-4.mol

Synonyms:3-biphenyl-1,2-dicarba-closo-dodecaborane

Chemical Property of 3-biphenyl-1,2-dicarba-closo-dodecaborane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 3-biphenyl-1,2-dicarba-closo-dodecaborane

There total 1 articles about 3-biphenyl-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

3-iodo-1,2-dicarba-closo-dodecaborane (137495-63-7) + 4-biphenylylmagnesium bromide (3315-91-1) → 3-biphenyl-1,2-dicarba-closo-dodecaborane (392250-97-4)

Guidance literature:

With [PdCl₂(PPh₃)2]; CuI; In tetrahydrofuran; to stirred soln. of B-compound in THF at 0°C was added soln. of Mg-compound in THF, stirred at room temp. for 30 min, Pd-complex and CuI were added, refluxed for 3 ds under N2; solvent was removed, Et2O was added, aq. HCl was added, organic layer was sepd., aq. layer was etxd. with Et2O, washed with water, dried over MgSO4, solvent was removed, silica gel chromy. with CH2Cl2/hexane; elem. anal.;

DOI:10.1021/ic010493o

upstream raw materials:

3-iodo-1,2-dicarba-closo-dodecaborane

4-biphenylylmagnesium bromide