phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

Base Information

Chemical Name:phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane
CAS No.:1452822-36-4
Molecular Formula:C₂₇H₂₈F₄OS
Molecular Weight:476.578
Hs Code.:

Synonyms:phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

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Technology Process of phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

There total 7 articles about phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1452822-15-9
C₂₁H₂₃BrF₄O

: 108-98-5
thiophenol

: 1452822-36-4
phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

Guidance literature:: With sodium dithionite; 3-Methylpyridine; In N,N-dimethyl-formamide; at 20 ℃; for 48h; Inert atmosphere;
DOI:10.1002/chem.201203315

Reference yield: 59.0%

: 1452822-15-9
C₂₁H₂₃BrF₄O

: 882-33-7
diphenyldisulfane

: 1452822-36-4
phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

Guidance literature:: C₂₁H₂₃BrF₄O; With tert.-butyl lithium; In tetrahydrofuran; at -100 - -95 ℃; for 2h; Inert atmosphere;

diphenyldisulfane; In tetrahydrofuran; at -95 - -80 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.201203315

Reference yield:

: 57477-93-7
hydrazone of p-bromobenzaldehyde

: 1452822-36-4
phenyl(1,1,2,2-tetrafluoro-3-(4'-(hexyloxy)biphenyl-4-yl)propyl)sulfane

Guidance literature:: Multi-step reaction with 3 steps

1.1: copper(l) chloride

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / 1,2-dimethoxyethane; water / Reflux; Inert atmosphere

3.1: tert.-butyl lithium / tetrahydrofuran / 2 h / -100 - -95 °C / Inert atmosphere

3.2: 2 h / -95 - -80 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tert.-butyl lithium; potassium carbonate; copper(l) chloride; In tetrahydrofuran; 1,2-dimethoxyethane; water; 2.1: |Suzuki Coupling;
DOI:10.1002/chem.201203315