Cyclopentadienylmagnesiumchloride

Base Information

• Chemical Name: Cyclopentadienylmagnesiumchloride
• CAS No.: 34766-85-3
• Molecular Formula: C5H5 Cl Mg
• Molecular Weight: 124.853
• Hs Code.: 2931900090
• European Community (EC) Number: 609-027-8
• DSSTox Substance ID: DTXSID601279921
• Mol file: 34766-85-3.mol

Synonyms:34766-85-3;SCHEMBL18173779;Cyclopentadienyl magnesium chloride;UCVIZTDOJLBADJ-UHFFFAOYSA-M;DTXSID601279921;MFCD02093383;CYCLOPENTADIENYLMAGNESIUMCHLORIDE;Chloro-2,4-cyclopentadien-1-ylmagnesium;Cyclopentadienylmagnesium chloride 1.0 M in THF

Chemical Property of Cyclopentadienylmagnesiumchloride

Chemical Property:

• PSA: 0.00000
• LogP: 1.82350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 123.9930195
• Heavy Atom Count: 7
• Complexity: 27.3

Purity/Quality:

99% ^*data from raw suppliers

CYCLOPENTADIENYLMAGNESIUM CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH-]1C=CC=C1.[Mg+2].[Cl-]

Technology Process of Cyclopentadienylmagnesiumchloride

There total 1 articles about Cyclopentadienylmagnesiumchloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dicyclopentadienylmagnesium (63757-86-8) → cyclopentadienyl magnesium chloride (34766-85-3,11112-17-7)

Guidance literature:

With gallium(III) chloride; In diethyl ether; toluene; at -30 ℃; for 168h;

DOI:10.1016/0022-328X(93)80059-K

Reference yield: 91.7%

4-iodobut-1-ene (7766-51-0) + cyclopentadienyl magnesium chloride (34766-85-3,11112-17-7) → 3-butenylcyclopentadiene

Guidance literature:

In tetrahydrofuran; at 35 - 50 ℃;

Reference yield: 82.0%

cyclopentadienyl magnesium chloride (34766-85-3,11112-17-7) + diphenylphosphane (829-85-6) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 1-cyclopenta-1,3-dienyl-3-diphenylphosphanyl-propan-2-ol + 1,3-Bis(diphenylphosphanyl)-2-propanol (60219-90-1)

Guidance literature:

diphenylphosphane; epichlorohydrin; With n-butyllithium; In tetrahydrofuran; at 25 ℃; for 0.5h;

cyclopentadienyl magnesium chloride; In tetrahydrofuran; at 25 ℃; for 15h;

upstream raw materials:

dicyclopentadienylmagnesium

Downstream raw materials:

1,3-Bis(diphenylphosphanyl)-2-propanol

1,1-bis(diphenylphoshpanylmethyl)-1-(cyclopentadienylmethyl)ethane

zirconocene dichloride

5-ethylcyclopentadiene