2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE
• CAS No.: 34589-46-3
• Molecular Formula: C8H9BrMg
• Molecular Weight: 209.368
• Hs Code.: 29310099
• Mol file: 34589-46-3.mol

Synonyms:2,4-Dimethylphenylmagnesium bromide solution;

Chemical Property of 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE

Chemical Property:

• Boiling Point: 65 °C
• Flash Point: 1 °F
• PSA: 0.00000
• Density: 0.946 g/mL at 25 °C
• LogP: 2.94920
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Reacts with water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,4-Dimethylphenylmagnesium bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F;C
• Hazard Codes: F,C
• Statements: 11-14-19-22-34-40-37
• Safety Statements: 16-26-33-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE

There total 2 articles about 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-2,4-dimethylbenzene (583-70-0) → (2,4-dimethylphenyl)magnesium bromide (34589-46-3)

Guidance literature:

With magnesium; In tetrahydrofuran; at 0 ℃;

Reference yield:

→ (2,4-dimethylphenyl)magnesium bromide (34589-46-3)

Guidance literature:

Reference yield: 96.0%

1-Fluoro-octane (463-11-6) + (2,4-dimethylphenyl)magnesium bromide (34589-46-3) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → (E)-1-(2,4-dimethylphenyl)-6-vinyltetradec-2-ene

Guidance literature:

With nickel(II) bromide dimethoxyethane; In tetrahydrofuran; at -78 - 40 ℃; for 10h; regioselective reaction; Inert atmosphere;

DOI:10.1002/anie.201601126

upstream raw materials:

1-bromo-2,4-dimethylbenzene

Downstream raw materials:

1-ethyl-2,4-dimethyl-benzene

3-chloro-2-(2,4-dimethyl-benzoyl)-benzoic acid

2-(2,4-dimethyl-benzoyl)-3,6-dimethyl-benzoic acid

2,4-dimethyl-1-(1,1,3-trimethyl-butyl)-benzene

Refernces

• 1、 -. "Method for producing alkyl-bridged ligand systems and transition metal compounds". . . Retrieved 2008/06/13.