(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Base Information

Chemical Name:(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol
CAS No.:868759-79-9
Molecular Formula:C₂₃H₂₆O₅S
Molecular Weight:414.522
Hs Code.:

Synonyms:(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

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Chemical Property of (2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

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Technology Process of (2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

There total 3 articles about (2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 868759-78-8
(2R,4aR,6S,7R,8R,8aS)-6-Allylsulfanyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 100-39-0
benzyl bromide

: 868759-79-9
(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Guidance literature:: (2R,4aR,6S,7R,8R,8aS)-6-Allylsulfanyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol; With BuSnO; cesium fluoride; In toluene; for 3h; Heating;

benzyl bromide; In N,N-dimethyl-formamide; for 12h;
DOI:10.1055/s-2005-872244

Reference yield:

: (2S,3R,4S,5S,6R)-2-Allylsulfanyl-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

: 868759-79-9
(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 67 percent / p-TsOH / dimethylformamide / 2 h / 50 °C

2.1: BuSnO; CsF / toluene / 3 h / Heating

2.2: 86 percent / dimethylformamide / 12 h

With BuSnO; toluene-4-sulfonic acid; cesium fluoride; In N,N-dimethyl-formamide; toluene;
DOI:10.1055/s-2005-872244

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 868759-79-9
(2R,4aR,6S,7R,8R,8aR)-6-Allylsulfanyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 67 percent / p-TsOH / dimethylformamide / 2 h / 50 °C

2.1: BuSnO; CsF / toluene / 3 h / Heating

2.2: 86 percent / dimethylformamide / 12 h

With BuSnO; toluene-4-sulfonic acid; cesium fluoride; In N,N-dimethyl-formamide; toluene;
DOI:10.1055/s-2005-872244