(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

Base Information

Chemical Name:(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde
CAS No.:1225377-86-5
Molecular Formula:C₄₃H₅₆N₄OSi
Molecular Weight:673.029
Hs Code.:

(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

Synonyms:(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

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Chemical Property of (5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

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Technology Process of (5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

There total 32 articles about (5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 1225377-84-3
2-((4aR,5R,7S,8aS)-8a-Ethynyl-1-formyl-7-methyldecahydroquinolin-5-yl)acetonitrile

: 1225377-80-9
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

: 1225377-86-5
(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

Guidance literature:: With dicarbonylcyclopentadienylcobalt; triphenylphosphine; In 1,4-dioxane; at 140 ℃;
DOI:10.1016/j.bmcl.2014.05.060

Reference yield: 42.0%

: 1225377-84-3
2-((4aR,5R,7S,8aS)-8a-Ethynyl-1-formyl-7-methyldecahydroquinolin-5-yl)acetonitrile

: 1225377-80-9
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

: 1225377-86-5
(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

: 1225377-85-4
(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1′-benzyl-16,16′-dimethyl-11-(trimethylsilyl)-1′,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15′,16,16′,17,17′-octadecahydro[10,10′-bi(5,10bpropano-1,7phenanthroline)]-1-(15H)-carbaldehyde

Guidance literature:: With dicarbonylcyclopentadienylcobalt; triphenylphosphine; In 1,4-dioxane; at 140 ℃; for 24h; Solvent; Temperature; Concentration; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo400695c

Reference yield: 36.0%

: 1225377-84-3
2-((4aR,5R,7S,8aS)-8a-Ethynyl-1-formyl-7-methyldecahydroquinolin-5-yl)acetonitrile

: 1225377-80-9
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

: C₃₆H₅₀N₄OSi

: 1225377-86-5
(5R,5′R,6S,6′S,14R,14′R,16R,16′R)-1-Benzyl-16,16′-dimethyl-10′-(trimethylsilyl)-1,2,2′,3,3′,4,4′,5,5′,6,6′,7,7′,15,16,16′,17,17′-octadecahydro[10,11′-bi(5,10b-propano1,7-phenanthroline)]-1′(15′H)-carbaldehyde

Guidance literature:: With dicarbonylcyclopentadienylcobalt; triphenylphosphine; In 1,4-dioxane; at 140 ℃; for 24h; regioselective reaction; Inert atmosphere; Sealed tube; Degassing;
DOI:10.1021/ja101956x