14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene

Base Information

• Chemical Name: 14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene
• CAS No.: 80468-66-2
• Molecular Formula: C₂₂H₃₂O₂S
• Molecular Weight: 360.561
• Mol file: 80468-66-2.mol

Synonyms:14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene

Chemical Property of 14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene

There total 1 articles about 14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

14-methyl-15-phenylsulfonyl-12-pentadecanolide (85037-93-0) → 14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene (80468-66-2)

Guidance literature:

With potassium hydroxide; In toluene; at 50 ℃; for 1h;

DOI:10.1002/hlca.19830660817

Reference yield:

14-methyl-13-phenylsulfonylbicyclo<10.3.0>pentadec-1(12)-ene (80468-66-2) → 2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-2-methyl-1H-cyclopentacyclododecene (21890-09-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / KOH / toluene; dimethylsulfoxide / 15 h / Heating

2: H₂ / 10percent Pd/C / toluene / 0.25 h / 100 °C

With potassium hydroxide; hydrogen; palladium on activated charcoal; In dimethyl sulfoxide; toluene;

DOI:10.1002/hlca.19830660817

upstream raw materials:

14-methyl-15-phenylsulfonyl-12-pentadecanolide

Downstream raw materials:

2,3,4,5,6,7,8,9,10,11,12,13-dodecahydro-2-methyl-1H-cyclopentacyclododecene