3-isopropenyl-2-vinylcyclohex-1-ene

Base Information

• Chemical Name: 3-isopropenyl-2-vinylcyclohex-1-ene
• CAS No.: 83719-64-6
• Molecular Formula: C₁₁H₁₆
• Molecular Weight: 148.248
• Mol file: 83719-64-6.mol

Synonyms:3-isopropenyl-2-vinylcyclohex-1-ene

Chemical Property of 3-isopropenyl-2-vinylcyclohex-1-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-isopropenyl-2-vinylcyclohex-1-ene

There total 22 articles about 3-isopropenyl-2-vinylcyclohex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl 2-(2-oxocyclohexyl)acetate (24731-17-7) → 3-isopropenyl-2-vinylcyclohex-1-ene (83719-64-6)

Guidance literature:

Multi-step reaction with 10 steps

1: SO₂Cl₂

2: DBU / hexane / 0.17 h / 35 °C

3: 1.) DMS, 2.) NaOEt / 1.) Et₂O, 2.) EtOH

4: p-TsOH / benzene

5: LiAlH₄ / diethyl ether

6: 1.) o-NO₂C₆H₄SeCN, n-Bu₃P, 2.) H₂O₂ / 1.) THF

7: AcOH, H₂O / 45 - 55 °C

8: Li, NH₃ / -78 °C

9: 80 percent / Hg(OAc)2 / 21.5 h / Heating

10: 3 h / 312 °C

With lithium aluminium tetrahydride; sulfuryl dichloride; ortho-nitrophenyl selenocyanate; 2,3-dimercapto-succinic acid; tributylphosphine; mercury(II) diacetate; ammonia; water; dihydrogen peroxide; sodium ethanolate; lithium; toluene-4-sulfonic acid; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In diethyl ether; hexane; benzene;

DOI:10.1021/ja00389a048

Reference yield:

2-(6-Oxocyclohex-1-enyl) acetate d'ethyle (24124-06-9) → 3-isopropenyl-2-vinylcyclohex-1-ene (83719-64-6)

Guidance literature:

Multi-step reaction with 8 steps

1: 1.) DMS, 2.) NaOEt / 1.) Et₂O, 2.) EtOH

2: p-TsOH / benzene

3: LiAlH₄ / diethyl ether

4: 1.) o-NO₂C₆H₄SeCN, n-Bu₃P, 2.) H₂O₂ / 1.) THF

5: AcOH, H₂O / 45 - 55 °C

6: Li, NH₃ / -78 °C

7: 80 percent / Hg(OAc)2 / 21.5 h / Heating

8: 3 h / 312 °C

With lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; 2,3-dimercapto-succinic acid; tributylphosphine; mercury(II) diacetate; ammonia; water; dihydrogen peroxide; sodium ethanolate; lithium; toluene-4-sulfonic acid; acetic acid; In diethyl ether; benzene;

DOI:10.1021/ja00389a048

Reference yield:

trans-2-ethenyl-3-(1-methylethenyl)cyclohexanone (78828-54-3) → 3-isopropenyl-2-vinylcyclohex-1-ene (83719-64-6)

Guidance literature:

Multi-step reaction with 3 steps

1: Li, NH₃ / -78 °C

2: 80 percent / Hg(OAc)2 / 21.5 h / Heating

3: 3 h / 312 °C

With mercury(II) diacetate; ammonia; lithium;

DOI:10.1021/ja00389a048

upstream raw materials:

(1RS,2RS,3RS)-3-isopropenyl-2-vinylcyclohex-1-yl vinyl ether

(1R*,2R*,3S*)-3-isopropenyl-2-vinylcyclohex-1-yl vinyl ether

(1RS,2SR,3RS)-3-isopropenyl-2-vinylcyclohex-1-yl vinyl ether

ethyl 2-(2-oxocyclohexyl)acetate