Technology Process of (1RS,2SR,3RS)-3-isopropenyl-2-vinylcyclohex-1-yl vinyl ether
There total 31 articles about (1RS,2SR,3RS)-3-isopropenyl-2-vinylcyclohex-1-yl vinyl ether which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 9 steps
1: SO2Cl2
2: DBU / hexane / 0.17 h / 35 °C
3: 1.) DMS, 2.) NaOEt / 1.) Et2O, 2.) EtOH
4: p-TsOH / benzene
5: LiAlH4 / diethyl ether
6: 1.) o-NO2C6H4SeCN, n-Bu3P, 2.) H2O2 / 1.) THF
7: AcOH, H2O / 45 - 55 °C
8: Li, NH3 / -78 °C
9: 80 percent / Hg(OAc)2 / 21.5 h / Heating
With
lithium aluminium tetrahydride; sulfuryl dichloride; ortho-nitrophenyl selenocyanate; 2,3-dimercapto-succinic acid; tributylphosphine; mercury(II) diacetate; ammonia; water; dihydrogen peroxide; sodium ethanolate; lithium; toluene-4-sulfonic acid; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene;
In
diethyl ether; hexane; benzene;
DOI:10.1021/ja00389a048
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 1.) DMS, 2.) NaOEt / 1.) Et2O, 2.) EtOH
2: p-TsOH / benzene
3: LiAlH4 / diethyl ether
4: 1.) o-NO2C6H4SeCN, n-Bu3P, 2.) H2O2 / 1.) THF
5: AcOH, H2O / 45 - 55 °C
6: Li, NH3 / -78 °C
7: 80 percent / Hg(OAc)2 / 21.5 h / Heating
With
lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; 2,3-dimercapto-succinic acid; tributylphosphine; mercury(II) diacetate; ammonia; water; dihydrogen peroxide; sodium ethanolate; lithium; toluene-4-sulfonic acid; acetic acid;
In
diethyl ether; benzene;
DOI:10.1021/ja00389a048
