7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:86520-61-8
Molecular Formula:C₂₂H₃₃NO₁₀
Molecular Weight:471.505
Hs Code.:

Synonyms:7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Chemical Property of 7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Technology Process of 7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 7 articles about 7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 106294-97-7
7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 86520-61-8
7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: With acetic acid; In water; at 80 ℃; for 1h;
DOI:10.1016/0008-6215(86)80016-7

Reference yield:

: 86520-56-1
methyl 10-phenyl-3,6,9-trioxadecanoate

: 86520-61-8
7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 91 percent / H₂ / 10percent Pd/C / methanol / 18 h

2: 67.8 percent / calcium sulfate, mercuric cyanide / CH₂Cl₂ / 30 h / Ambient temperature

3: 86.5 percent / NaOMe / methanol / 2 h / Ambient temperature

4: 84 percent / p-toluenesulfonic acid monohydrate / 1 h / 65 - 100 °C

5: 1.) barium oxide, barium hydroxide octahydrate / 1.) DMF, 3 h, RT, 2.) MeOH, ether

6: 65 percent / 80percent acetic acid / H₂O / 1 h / 80 °C

With calcium sulfate; barium hydroxide octahydrate; hydrogen; sodium methylate; mercury(II) cyanide; toluene-4-sulfonic acid; acetic acid; barium(II) oxide; palladium on activated charcoal; In methanol; dichloromethane; water;
DOI:10.1016/0008-6215(86)80016-7

Reference yield:

: 86520-57-2
7-methoxycarbonyl-3,6-dioxa-1-heptanol

: 86520-61-8
7-methoxycarbonyl-3,6-dioxaheptyl 2-acetamido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 67.8 percent / calcium sulfate, mercuric cyanide / CH₂Cl₂ / 30 h / Ambient temperature

2: 86.5 percent / NaOMe / methanol / 2 h / Ambient temperature

3: 84 percent / p-toluenesulfonic acid monohydrate / 1 h / 65 - 100 °C

4: 1.) barium oxide, barium hydroxide octahydrate / 1.) DMF, 3 h, RT, 2.) MeOH, ether

5: 65 percent / 80percent acetic acid / H₂O / 1 h / 80 °C

With calcium sulfate; barium hydroxide octahydrate; sodium methylate; mercury(II) cyanide; toluene-4-sulfonic acid; acetic acid; barium(II) oxide; In methanol; dichloromethane; water;
DOI:10.1016/0008-6215(86)80016-7