iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene

Base Information

• Chemical Name: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene
• CAS No.: 80697-72-9
• Molecular Formula: 0CH₂Cl₂*C₅₃H₃₂ClFeN₅O₂S
• Molecular Weight: 915.469
• Mol file: 80697-72-9.mol

Synonyms:iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene

Chemical Property of iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene

Chemical Property:

Purity/Quality:

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Technology Process of iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene

There total 1 articles about iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + 2-trichloromethylthio-1H-isoindole-1,3(2H)-dione (133-07-3) → iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene (80697-72-9)

Guidance literature:

With sodium dithionite; In dichloromethane; water; aq. soln. of Na2S2O4 adding to a soln. of Fe(III) complex in CH2Cl2, stirring for 0.25 h under Ar, ligand soln. in CH2Cl2 adding, stirring for 2 h, aq. layer removing, organic layer washing with H2O, solvent removing by Ar bubbling; identified by elem. anal., UV, IR, mass and NMR spectra;

DOI:10.1021/ic00135a066

Reference yield:

iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene (80697-72-9) → thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II) (67583-11-3)

Guidance literature:

With iron(II) chloride; In chloroform-d1; acetonitrile; byproducts: C6H5CH2Cl; satd. soln. of Fe(II) salt in MeCN adding to a soln. of Fe(II) complex in CDCl3; monitoring by NMR spectrum; reaction is complete within 3 h at34°C; detd. by IR, UV and NMR spectra;

DOI:10.1021/ic00135a066

upstream raw materials:

meso-tetraphenylporphyrin iron(III) chloride

2-trichloromethylthio-1H-isoindole-1,3(2H)-dione

Downstream raw materials:

thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II)

Refernces